Matches in SemOpenAlex for { <https://semopenalex.org/work/W1991398726> ?p ?o ?g. }
- W1991398726 endingPage "1742" @default.
- W1991398726 startingPage "1736" @default.
- W1991398726 abstract "A mechanism for the regioselective silaboration of terminal allene by a palladium catalyst has been studied theoretically. The overall reaction scheme has been examined in particular to determine the mechanism of the regioselectivity. The present catalytic reaction is exothermic and the rate-determining step is the insertion of allene into the Pd−B bond of the Pd complex. σ-Allylic and π-allylic complexes exist as intermediates and play an important role in the regioselectivity. Selective insertion of the unsubstituted C═C bond into the Pd−B bond produces the most stable σ-allylic complex, which converts to the π-allylic complex while maintaining the Pd−O coordination. The selective formation of the specific σ-allylic complex and the large activation barrier between two isomeric π-allylic complexes dominantly determines the regioselectivity of the present reaction. The major-product complex is less stable than the minor-product complex, and therefore kinetic control is predominant in the present reaction." @default.
- W1991398726 created "2016-06-24" @default.
- W1991398726 creator A5006917268 @default.
- W1991398726 creator A5017816540 @default.
- W1991398726 creator A5034939239 @default.
- W1991398726 creator A5035037742 @default.
- W1991398726 creator A5067334549 @default.
- W1991398726 creator A5080091950 @default.
- W1991398726 creator A5088210431 @default.
- W1991398726 date "2008-03-18" @default.
- W1991398726 modified "2023-09-27" @default.
- W1991398726 title "A Mechanism for the Palladium-Catalyzed Regioselective Silaboration of Allene: A Theoretical Study" @default.
- W1991398726 cites W1580863239 @default.
- W1991398726 cites W1968202660 @default.
- W1991398726 cites W1972962756 @default.
- W1991398726 cites W1978397019 @default.
- W1991398726 cites W1982356449 @default.
- W1991398726 cites W2008135795 @default.
- W1991398726 cites W2016107068 @default.
- W1991398726 cites W2016492540 @default.
- W1991398726 cites W2022246625 @default.
- W1991398726 cites W2023271753 @default.
- W1991398726 cites W2043858195 @default.
- W1991398726 cites W2060468035 @default.
- W1991398726 cites W2068617439 @default.
- W1991398726 cites W2072588757 @default.
- W1991398726 cites W2084009405 @default.
- W1991398726 cites W2086957099 @default.
- W1991398726 cites W2088303710 @default.
- W1991398726 cites W2094771470 @default.
- W1991398726 cites W2143981217 @default.
- W1991398726 cites W2162512315 @default.
- W1991398726 cites W2950471947 @default.
- W1991398726 cites W2950496793 @default.
- W1991398726 cites W2950862946 @default.
- W1991398726 cites W2951148672 @default.
- W1991398726 cites W2951177329 @default.
- W1991398726 cites W2951752868 @default.
- W1991398726 cites W2952898841 @default.
- W1991398726 cites W2953185123 @default.
- W1991398726 doi "https://doi.org/10.1021/om070110f" @default.
- W1991398726 hasPublicationYear "2008" @default.
- W1991398726 type Work @default.
- W1991398726 sameAs 1991398726 @default.
- W1991398726 citedByCount "47" @default.
- W1991398726 countsByYear W19913987262012 @default.
- W1991398726 countsByYear W19913987262013 @default.
- W1991398726 countsByYear W19913987262014 @default.
- W1991398726 countsByYear W19913987262015 @default.
- W1991398726 countsByYear W19913987262016 @default.
- W1991398726 countsByYear W19913987262017 @default.
- W1991398726 countsByYear W19913987262018 @default.
- W1991398726 countsByYear W19913987262019 @default.
- W1991398726 countsByYear W19913987262020 @default.
- W1991398726 countsByYear W19913987262021 @default.
- W1991398726 countsByYear W19913987262022 @default.
- W1991398726 crossrefType "journal-article" @default.
- W1991398726 hasAuthorship W1991398726A5006917268 @default.
- W1991398726 hasAuthorship W1991398726A5017816540 @default.
- W1991398726 hasAuthorship W1991398726A5034939239 @default.
- W1991398726 hasAuthorship W1991398726A5035037742 @default.
- W1991398726 hasAuthorship W1991398726A5067334549 @default.
- W1991398726 hasAuthorship W1991398726A5080091950 @default.
- W1991398726 hasAuthorship W1991398726A5088210431 @default.
- W1991398726 hasConcept C120095180 @default.
- W1991398726 hasConcept C155647269 @default.
- W1991398726 hasConcept C161790260 @default.
- W1991398726 hasConcept C178790620 @default.
- W1991398726 hasConcept C185592680 @default.
- W1991398726 hasConcept C2778652500 @default.
- W1991398726 hasConcept C45119746 @default.
- W1991398726 hasConcept C502130503 @default.
- W1991398726 hasConcept C59759590 @default.
- W1991398726 hasConcept C65024703 @default.
- W1991398726 hasConcept C68381374 @default.
- W1991398726 hasConcept C71240020 @default.
- W1991398726 hasConceptScore W1991398726C120095180 @default.
- W1991398726 hasConceptScore W1991398726C155647269 @default.
- W1991398726 hasConceptScore W1991398726C161790260 @default.
- W1991398726 hasConceptScore W1991398726C178790620 @default.
- W1991398726 hasConceptScore W1991398726C185592680 @default.
- W1991398726 hasConceptScore W1991398726C2778652500 @default.
- W1991398726 hasConceptScore W1991398726C45119746 @default.
- W1991398726 hasConceptScore W1991398726C502130503 @default.
- W1991398726 hasConceptScore W1991398726C59759590 @default.
- W1991398726 hasConceptScore W1991398726C65024703 @default.
- W1991398726 hasConceptScore W1991398726C68381374 @default.
- W1991398726 hasConceptScore W1991398726C71240020 @default.
- W1991398726 hasIssue "8" @default.
- W1991398726 hasLocation W19913987261 @default.
- W1991398726 hasOpenAccess W1991398726 @default.
- W1991398726 hasPrimaryLocation W19913987261 @default.
- W1991398726 hasRelatedWork W1991398726 @default.
- W1991398726 hasRelatedWork W2038502801 @default.
- W1991398726 hasRelatedWork W2091037298 @default.
- W1991398726 hasRelatedWork W2103958276 @default.
- W1991398726 hasRelatedWork W2162674423 @default.
- W1991398726 hasRelatedWork W2177195043 @default.