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• W1991402529 abstract "The 250 MHz 1H NMR spectrum of L-proline is comprehensively analysed by computer simulation for different pH values. A fast endo–exo interconversion has already been proposed from chemical shift and coupling constant data. A critical comparison of the vicinal coupling constants leads to the conclusion that in basic solution the equilibrium is shifted towards a more endo conformation. The position of the carboxylic plane in the ring space is given by the relative intramolecular chemical shift of the geminal protons and by the typical patterns of the Hα multiplet. These results are applied to the analysis of the spectra of ProNH2 and AcProNH2." @default.
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• W1991402529 date "1975-02-01" @default.
• W1991402529 modified "2023-09-23" @default.
• W1991402529 title "A NMR investigation of proline and its derivatives. II—Conformational implications of the1H NMR spectrum of L-proline at different pH" @default.
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• W1991402529 doi "https://doi.org/10.1002/mrc.1270070202" @default.
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