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- W1991413400 abstract "A shock tube has been employed to study the dissociation of HCl in an argon diluent in the temperature range 3300°—5400°K and at total gas concentrations of 0.21, 0.42, and 0.84×10−5 moles/cc. The rate constant was determined to be k1=1.92×1011T12exp(−69 700/RT) cc/mole·sec. Experiments were conducted employing gas mixtures containing 1% HCl and 99% Ar; 2% HCl and 98% Ar; and 1% H2, 2% HCl, and 97% Ar. The inclusion of H2 did not noticeably affect the rate of dissociation of HCl.The dissociation of HCl is compared to that of H2, which possesses a similar dissociation energy. It is shown that the rate constant for the dissociation of HCl has a much lower activation energy than that of H2. The possible reasons for this lower activation energy are presented and discussed." @default.
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- W1991413400 date "1966-12-01" @default.
- W1991413400 modified "2023-09-28" @default.
- W1991413400 title "Gaseous Reaction Rates at High Temperatures. II. The Dissociation of Hydrogen Chloride" @default.
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- W1991413400 doi "https://doi.org/10.1063/1.1727456" @default.
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