Matches in SemOpenAlex for { <https://semopenalex.org/work/W1991423616> ?p ?o ?g. }
Showing items 1 to 65 of
65
with 100 items per page.
- W1991423616 endingPage "392" @default.
- W1991423616 startingPage "379" @default.
- W1991423616 abstract "Abstract Solid complexes of boron decachloro-o-carborane and boron decachloro-m-carborane (B10Cl10C2H2) with some oxygen and nitrogen bases have been investigated by infrared and Raman spectroscopy. Complexes containing CH · · O hydrogen bonds are characterized by a relative CH stretching frequency shift up to 12% and a halfwidth of the νCH band up to 220 cm−1. CH · · N hydrogen bonds, with trimethylamine for example, are stronger with a relative shift of about 18% and ν 1 2 of about 500 cm−1. Triethylamine complexes, however, form a NH+ · · C− proton transfer hydrogen bond while pyridine can give either CH · · N or C− · · +HN hydrogen-bonded adducts depending on the solvent and temperature. The CH · · N↔c− · · +HN equilibrium appears to be shifted towards ion-pair formation at considerably smaller enthalpy values compared to the OH · · N↔O− · · +HN system. CH and NH stretching frequencies are correlated with the acidity of the donor and the basicity of acceptor molecules." @default.
- W1991423616 created "2016-06-24" @default.
- W1991423616 creator A5024540155 @default.
- W1991423616 creator A5030449931 @default.
- W1991423616 creator A5043766338 @default.
- W1991423616 creator A5054126313 @default.
- W1991423616 date "1983-07-01" @default.
- W1991423616 modified "2023-09-27" @default.
- W1991423616 title "Vibrational study of strong CH · middot; X hydrogen bonds in solid complexes of boron decachlorocarboranes" @default.
- W1991423616 cites W1965503565 @default.
- W1991423616 cites W2007183728 @default.
- W1991423616 cites W2014384154 @default.
- W1991423616 cites W2041768785 @default.
- W1991423616 cites W2047696782 @default.
- W1991423616 cites W2063527501 @default.
- W1991423616 cites W2065981852 @default.
- W1991423616 cites W2067310855 @default.
- W1991423616 cites W2070418493 @default.
- W1991423616 cites W2079084093 @default.
- W1991423616 cites W2234998704 @default.
- W1991423616 doi "https://doi.org/10.1016/0022-2860(83)90102-3" @default.
- W1991423616 hasPublicationYear "1983" @default.
- W1991423616 type Work @default.
- W1991423616 sameAs 1991423616 @default.
- W1991423616 citedByCount "9" @default.
- W1991423616 countsByYear W19914236162016 @default.
- W1991423616 crossrefType "journal-article" @default.
- W1991423616 hasAuthorship W1991423616A5024540155 @default.
- W1991423616 hasAuthorship W1991423616A5030449931 @default.
- W1991423616 hasAuthorship W1991423616A5043766338 @default.
- W1991423616 hasAuthorship W1991423616A5054126313 @default.
- W1991423616 hasConcept C112887158 @default.
- W1991423616 hasConcept C178790620 @default.
- W1991423616 hasConcept C185592680 @default.
- W1991423616 hasConcept C32909587 @default.
- W1991423616 hasConcept C501308230 @default.
- W1991423616 hasConcept C512968161 @default.
- W1991423616 hasConcept C8010536 @default.
- W1991423616 hasConceptScore W1991423616C112887158 @default.
- W1991423616 hasConceptScore W1991423616C178790620 @default.
- W1991423616 hasConceptScore W1991423616C185592680 @default.
- W1991423616 hasConceptScore W1991423616C32909587 @default.
- W1991423616 hasConceptScore W1991423616C501308230 @default.
- W1991423616 hasConceptScore W1991423616C512968161 @default.
- W1991423616 hasConceptScore W1991423616C8010536 @default.
- W1991423616 hasLocation W19914236161 @default.
- W1991423616 hasOpenAccess W1991423616 @default.
- W1991423616 hasPrimaryLocation W19914236161 @default.
- W1991423616 hasRelatedWork W1986541343 @default.
- W1991423616 hasRelatedWork W2024177088 @default.
- W1991423616 hasRelatedWork W2317458986 @default.
- W1991423616 hasRelatedWork W2328537149 @default.
- W1991423616 hasRelatedWork W2334816388 @default.
- W1991423616 hasRelatedWork W2344037851 @default.
- W1991423616 hasRelatedWork W2397355901 @default.
- W1991423616 hasRelatedWork W2950709676 @default.
- W1991423616 hasRelatedWork W3108833000 @default.
- W1991423616 hasRelatedWork W3136319118 @default.
- W1991423616 hasVolume "100" @default.
- W1991423616 isParatext "false" @default.
- W1991423616 isRetracted "false" @default.
- W1991423616 magId "1991423616" @default.
- W1991423616 workType "article" @default.