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- W1991441503 abstract "An electrochemically formed polyazulene(PAz), one of the electroconductive polycyclic hydrocarbons, was studied for its electrochemical properties in order to examine the possibility of utilizing it as a cathode active material of rechargeable lithium battery. The electrode kinetics of PAz film electrode, especially the anion doping‐undoping process, were investigated mainly with cyclic voltammetry and FFT impedance method. The cyclic voltammetric results of PAz film showed a highly reversible redox process. Cole‐Cole plots for PAz electrode obtained by impedance measurement as a function of doping potential were also found to offer an indication that PAz can be an excellent battery material. The charging‐discharging property, and the cyclability of a battery were then studied as a function of the film thickness of PAz cathode. The charging‐discharging behavior of was also compared with those of and batteries, which had been examined earlier. When compared with or batteries, a battery showed fairly high and constant discharge voltage (ca. 3.2V), while keeping 100% of coulombic yield. Inspection by SEM showed that the surface condition of PAz film greatly resembled that of polypyrrole, however, a 10 C cm−2 PAz film was prepared with thicker than polypyrrole formed with the same amount of charge of 10 C cm−2." @default.
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- W1991441503 date "1987-11-01" @default.
- W1991441503 modified "2023-10-11" @default.
- W1991441503 title "Application of Electrochemically Formed Polyazulene to Rechargeable Lithium Battery" @default.
- W1991441503 doi "https://doi.org/10.1149/1.2100265" @default.
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