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- W1991455109 abstract "Enthalpies of mixing of furan, methylfuran, tetrahydrofuran (THF), 1,4-dioxane and cyclopentanone with tetrachloroethane (TCE) were determined by microcalorimetry. All the systems were exothermic in nature, showing the following trend: THF > cyclopentanone > 1,4-dioxane > methylfuran > furan. Saturation of the ring led to a marked increase in the energy of intermolecular interaction. This was attributed to the specific interactions between oxygen and the H of TCE, oxygen and the Cl of TCE, and between the CH2 group and the Cl of TCE. This hypothesis was confirmed by a downfield shift in the NMR spectra on addition of TCE to pure THF, 1,4-dioxane and cyclopentanone." @default.
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- W1991455109 date "1995-07-01" @default.
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- W1991455109 title "Enthalpies of mixing of tetrachloroethane with furan, methylfuran, tetrahydrofuran, cyclopentanone and 1,4-dioxane" @default.
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- W1991455109 doi "https://doi.org/10.1016/0040-6031(94)02236-h" @default.
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