FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1991457590> ?p ?o ?g. }

• W1991457590 endingPage "7972" @default.
• W1991457590 startingPage "7963" @default.
• W1991457590 abstract "Methylpentaphenylsilole (MPPS) and tetraphenylethene (TPE) are two archetypal luminogens that show the novel effect of aggregation-induced emission (AIE). In this work, TPE moieties are attached to MPPS core as peripheral groups at 2,5- and 3,4-positions to generate new AIE luminogens. The resulting 2,5- and 3,4-BTPEMTPS adducts are weakly fluorescent in dilute solutions but become highly emissive as solid aggregates, verifying their AIE activities. Although weak in the absolute term, the emissions of the 2,5- and 3,4-BTPEMTPS luminogens are stronger than those of their parent forms of MPPS and TPE, due to the steric effect of the bulky TPE pedants on the intramolecular motions, especially the rotations of the phenyl rotors, in the BTPEMTPS systems. The emissions of 2,5-BTPEMTPS in the solution and aggregate states are more efficient and redder than those of 3,4-BTPEMTPS, revealing that the former is electronically more conjugated than the latter. Both the BTPEMTPS regioisomers are morphologically and thermally stable, showing high glass transition (Tg = 126 °C) and thermal-degradation temperatures (Td up to 400 °C). The AIE luminogens serve as excellent emitters in electroluminescence (EL) devices, with maximum luminance up to 12560 cd/m2. The EL deices using the blends of 2,5-BTPEMTPS and bis(tetraphenylethene) (BTPE) as emitting layers afford high current efficiencies (up to ∼7 cd/A) and external quantum efficiencies (up to ∼2.2%), thanks to the efficient energy transfer from the BTPE host to the 2,5-BTPEMTPS guest in the blending layer." @default.
• W1991457590 created "2016-06-24" @default.
• W1991457590 creator A5000254994 @default.
• W1991457590 creator A5000679682 @default.
• W1991457590 creator A5001424734 @default.
• W1991457590 creator A5007046138 @default.
• W1991457590 creator A5007782655 @default.
• W1991457590 creator A5034093082 @default.
• W1991457590 creator A5050859754 @default.
• W1991457590 creator A5071196133 @default.
• W1991457590 creator A5075299273 @default.
• W1991457590 creator A5077737058 @default.
• W1991457590 creator A5081061289 @default.
• W1991457590 date "2010-04-12" @default.
• W1991457590 modified "2023-10-17" @default.
• W1991457590 title "Steric Hindrance, Electronic Communication, and Energy Transfer in the Photo- and Electroluminescence Processes of Aggregation-Induced Emission Luminogens" @default.
• W1991457590 cites W1968779758 @default.
• W1991457590 cites W1969958909 @default.
• W1991457590 cites W1971393110 @default.
• W1991457590 cites W1973856006 @default.
• W1991457590 cites W1977420003 @default.
• W1991457590 cites W1979487830 @default.
• W1991457590 cites W1981754932 @default.
• W1991457590 cites W1982151759 @default.
• W1991457590 cites W1982673828 @default.
• W1991457590 cites W1984990803 @default.
• W1991457590 cites W1996778349 @default.
• W1991457590 cites W1996988470 @default.
• W1991457590 cites W2001838359 @default.
• W1991457590 cites W2005191958 @default.
• W1991457590 cites W2027825913 @default.
• W1991457590 cites W2028526435 @default.
• W1991457590 cites W2032185182 @default.
• W1991457590 cites W2033739947 @default.
• W1991457590 cites W2050326469 @default.
• W1991457590 cites W2053169144 @default.
• W1991457590 cites W2066458703 @default.
• W1991457590 cites W2067984650 @default.
• W1991457590 cites W2068169239 @default.
• W1991457590 cites W2071716143 @default.
• W1991457590 cites W2073822438 @default.
• W1991457590 cites W2083370747 @default.
• W1991457590 cites W2086128718 @default.
• W1991457590 cites W2093513857 @default.
• W1991457590 cites W2094989517 @default.
• W1991457590 cites W2105109249 @default.
• W1991457590 cites W2126415275 @default.
• W1991457590 cites W2127105620 @default.
• W1991457590 cites W2130752306 @default.
• W1991457590 cites W2140925678 @default.
• W1991457590 cites W2165344788 @default.
• W1991457590 cites W2950892829 @default.
• W1991457590 doi "https://doi.org/10.1021/jp910728x" @default.
• W1991457590 hasPublicationYear "2010" @default.
• W1991457590 type Work @default.
• W1991457590 sameAs 1991457590 @default.
• W1991457590 citedByCount "106" @default.
• W1991457590 countsByYear W19914575902012 @default.
• W1991457590 countsByYear W19914575902013 @default.
• W1991457590 countsByYear W19914575902014 @default.
• W1991457590 countsByYear W19914575902015 @default.
• W1991457590 countsByYear W19914575902016 @default.
• W1991457590 countsByYear W19914575902017 @default.
• W1991457590 countsByYear W19914575902018 @default.
• W1991457590 countsByYear W19914575902019 @default.
• W1991457590 countsByYear W19914575902020 @default.
• W1991457590 countsByYear W19914575902021 @default.
• W1991457590 countsByYear W19914575902022 @default.
• W1991457590 countsByYear W19914575902023 @default.
• W1991457590 crossrefType "journal-article" @default.
• W1991457590 hasAuthorship W1991457590A5000254994 @default.
• W1991457590 hasAuthorship W1991457590A5000679682 @default.
• W1991457590 hasAuthorship W1991457590A5001424734 @default.
• W1991457590 hasAuthorship W1991457590A5007046138 @default.
• W1991457590 hasAuthorship W1991457590A5007782655 @default.
• W1991457590 hasAuthorship W1991457590A5034093082 @default.
• W1991457590 hasAuthorship W1991457590A5050859754 @default.
• W1991457590 hasAuthorship W1991457590A5071196133 @default.
• W1991457590 hasAuthorship W1991457590A5075299273 @default.
• W1991457590 hasAuthorship W1991457590A5077737058 @default.
• W1991457590 hasAuthorship W1991457590A5081061289 @default.
• W1991457590 hasConcept C112613896 @default.
• W1991457590 hasConcept C120665830 @default.
• W1991457590 hasConcept C121332964 @default.
• W1991457590 hasConcept C159467904 @default.
• W1991457590 hasConcept C178790620 @default.
• W1991457590 hasConcept C185592680 @default.
• W1991457590 hasConcept C192562407 @default.
• W1991457590 hasConcept C201194858 @default.
• W1991457590 hasConcept C205507967 @default.
• W1991457590 hasConcept C2778987444 @default.
• W1991457590 hasConcept C2779227376 @default.
• W1991457590 hasConcept C31625292 @default.
• W1991457590 hasConcept C49040817 @default.
• W1991457590 hasConcept C521977710 @default.
• W1991457590 hasConcept C75079739 @default.
• W1991457590 hasConcept C75473681 @default.
• W1991457590 hasConcept C91881484 @default.

• next