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- W1991459405 abstract "Abstract The geochemical behavior of Re in oxidized arc magmas (Eastern Manus basin) and MORB has been reexamined. In the early differentiation stage of oxidized arc magmas, Yb, Cu, Au, Ag, and Re have a bulk partition coefficient (D) between the crystallized mineral assemblage (olivine, clinopyroxene, and plagioclase) and the residual melt on the order of 0.33 = D Yb ~ D Au > D Re > D Ag > D Cu , while in the late stage they have a bulk D between the crystallized mineral assemblage (clinopyroxene, plagioclase, magnetite, and monosulfide solid solution — MSS) and the residual melt on the order D Re > D Cu > D Au ≥ 1 > D Yb = 0.29 > D Ag . In oxidized arc magmas, Cu, Au, and Ag are primarily controlled by crystalline MSS, whereas Re is primarily controlled by magnetite and it has a MSS/silicate melt partition coefficient significantly lower than 20. Unlike oxidized arc magmas, most MORB are saturated with sulfide liquid. Based on the positive correlation of log (D Cu / D Re ) and ∆FMQ regardless of f S 2 , log (D Cu / D Re ) = 0.997ΔFMQ + 0.181 (R 2 = 0.99) (D = partition coefficient between sulfide liquid and silicate melt; FMQ = fayalite–magnetite–quartz oxygen buffer), the partition coefficient of Re between sulfide liquid and silicate melt for MORB is estimated to be in the range of 600–10,000 at f O 2 of FMQ to FMQ − 1, increasing with decreasing f O 2 . These partitioning data constrain that during MORB differentiation Re may be as compatible as Cu or Ag at relatively oxidized conditions (FMQ − 0.5 f O 2 f O 2" @default.
- W1991459405 created "2016-06-24" @default.
- W1991459405 creator A5008947832 @default.
- W1991459405 date "2014-10-01" @default.
- W1991459405 modified "2023-10-05" @default.
- W1991459405 title "Comparative geochemistry of rhenium in oxidized arc magmas and MORB and rhenium partitioning during magmatic differentiation" @default.
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- W1991459405 doi "https://doi.org/10.1016/j.chemgeo.2014.08.013" @default.
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