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- W1991471194 abstract "Reinvestigation of the Lewis acid catalyzed rearrangement of some open-chain permethyloligosilanes with the Al(Fe)Cl3 catalyst system exhibited several cases of additional reactivity: namely, a fragmentation/cyclization reaction. Introduction of (trimethylsilyl)methyl substituents into the oligosilane substrates strongly facilitated this reaction, yielding cyclic or bicyclic carbacyclosilanes. Investigations concerning the composition of the catalyst system indicated that the incorporation of about 0.1% FeCl3 into the AlCl3 lattice provided an effective catalyst." @default.
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- W1991471194 date "2011-07-11" @default.
- W1991471194 modified "2023-10-01" @default.
- W1991471194 title "Rearrangement/Fragmentation Reactions of Oligosilanes with Aluminum Chloride" @default.
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- W1991471194 doi "https://doi.org/10.1021/om1011165" @default.
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