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- W1991489420 abstract "A simple kinetic model is proposed to consider the effect of molecular interactions and molecular mobility on the breakdown of polymer chains. The parameter characterizing this effect was determined. It is shown that the mechanism proposed may result in the formation of a plateau and discontinuities on the force dependence of durability. According to the numerical evaluations a plateau can only be observed on the dependence of ln τ(σ) at very low temperatures under very stiff conditions existing for breakdown parameters and molecular mobility. Discontinuities in the dependence of ln τ(σ) on the other hand may be easily observed under ordinary conditions of experiments of polymer durability." @default.
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- W1991489420 date "1981-01-01" @default.
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- W1991489420 title "Effect of molecular interactions and molecular mobility on kinetics of breakdown of chemical bonds in a polymer" @default.
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- W1991489420 doi "https://doi.org/10.1016/0032-3950(81)90418-4" @default.
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