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- W1991510348 abstract "The reaction between π-(PhCHCHCOR)Fe(CO)3 (R = H, CH3, Ph) and L (L = PPh3, AsPh3, SbPh3) in acetone occurs in two steps. The products of the first step are the π-(PhCHCHCOR)Fe(CO)3L complexes, which in the second step yield Fe(CO)3L2 and π-(PhCHCHCOR)Fe(CO)2L. The kinetic results indicate that the first step is association of the substrate with the ligand. The variation of the ratio [Fe(CO)3L2]/[π-(PhCHCHCOR)Fe(CO)2L] with L suggests three different reaction paths for the second step." @default.
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- W1991510348 date "1975-04-01" @default.
- W1991510348 modified "2023-09-27" @default.
- W1991510348 title "The mechanism of substitution of π-(PhCHCHCOR)Fe(CO)3 complexes with PPh3, AsPh3 and SbPh3" @default.
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- W1991510348 doi "https://doi.org/10.1016/s0022-328x(00)91610-3" @default.
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