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• W1991566888 abstract "An aqueous suspension of zinc sulphide photocatalyses the dehydrodimerization of 3,4-dihydro-2H-pyran, 4-methyl-5,6-dihydro-2H-pyran and cyclohexene under concomitant hydrogen evolution. Maximum turn-over numbers are in the range of 3000 monolayers. While three regioisomers are obtained from the two first substrates, cyclohexene affords the 2,2′ isomer exclusively. The most reactive zinc sulphide samples have specific surface areas of about 100 m2 g−1 and an excess of sulphur at the surface. These samples do not suffer photocorrosion when irradiated in a suspension of pure water. However, this occurs with samples of lower surface area and excess zinc at the surface." @default.
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• W1991566888 date "1993-12-01" @default.
• W1991566888 modified "2023-09-26" @default.
• W1991566888 title "Heterogeneous photocatalysis XI. Zinc sulphide catalysed dehydrodimerization of dihydropyrans and cyclohexene" @default.
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• W1991566888 doi "https://doi.org/10.1016/1010-6030(93)80137-x" @default.
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