Matches in SemOpenAlex for { <https://semopenalex.org/work/W1991567315> ?p ?o ?g. }
- W1991567315 endingPage "7769" @default.
- W1991567315 startingPage "7758" @default.
- W1991567315 abstract "The preparation and structures of seven new silver(I) complexes involving the parent tris(pyrazolyl)methane unit, [C(pz)3], as the donor set, {[C6H5CH2OCH2C(pz)3]Ag}(BF4), {[C6H5CH2OCH2C(pz)3]2Ag3}(CF3SO3)3, {[HOCH2C(pz)3]Ag}(BF4), {[HOCH2C(pz)3]Ag}(CF3SO3), {[HC(pz)3]2Ag2(CH3CN)}(BF4)2, {[HC(pz)3]Ag}(PF6), and {[HC(pz)3]Ag}(CF3SO3), are reported. This project is based on a retro-design of our multitopic C6H6-n[CH2OCH2C(pz)3]n (pz = pyrazolyl ring, n = 2, 3, 4, and 6) family of ligands in such a way that each new ligand has one fewer organizational feature. The κ2−κ1 bonding mode of the [C(pz)3] units to two silvers, also observed with the multitopic ligands, is the dominant structural feature in all cases. Changing the counterion has important effects on the local structures and on crystal packing. When these structures are compared to similar ones based on the multitopic C6H6-n[CH2OCH2C(pz)3]n ligands, it has been shown that the presence of the rigid parts (central arene core and the [C(pz)3] units) are important in order to observe highly organized supramolecular structures. The presence of the flexible ether linkage is also crucial, allowing all noncovalent forces to manifest themselves in a cumulative and complementary manner." @default.
- W1991567315 created "2016-06-24" @default.
- W1991567315 creator A5027404750 @default.
- W1991567315 creator A5034938361 @default.
- W1991567315 creator A5041241032 @default.
- W1991567315 creator A5054353412 @default.
- W1991567315 date "2006-08-16" @default.
- W1991567315 modified "2023-09-24" @default.
- W1991567315 title "Crystal Retro-Engineering: Structural Impact on Silver(I) Complexes with Changing Complexity of Tris(pyrazolyl)methane Ligands" @default.
- W1991567315 cites W1898449009 @default.
- W1991567315 cites W1937416178 @default.
- W1991567315 cites W1963016962 @default.
- W1991567315 cites W1964277385 @default.
- W1991567315 cites W1964874570 @default.
- W1991567315 cites W1965272987 @default.
- W1991567315 cites W1966231476 @default.
- W1991567315 cites W1967344593 @default.
- W1991567315 cites W1969885133 @default.
- W1991567315 cites W1971109047 @default.
- W1991567315 cites W1972164051 @default.
- W1991567315 cites W1972646318 @default.
- W1991567315 cites W1975145848 @default.
- W1991567315 cites W1975501285 @default.
- W1991567315 cites W1981178187 @default.
- W1991567315 cites W1983607360 @default.
- W1991567315 cites W1989013147 @default.
- W1991567315 cites W1992160050 @default.
- W1991567315 cites W1999908724 @default.
- W1991567315 cites W2000625356 @default.
- W1991567315 cites W2000975220 @default.
- W1991567315 cites W2003004688 @default.
- W1991567315 cites W2003900696 @default.
- W1991567315 cites W2004863501 @default.
- W1991567315 cites W2006377435 @default.
- W1991567315 cites W2007203236 @default.
- W1991567315 cites W2010235932 @default.
- W1991567315 cites W2011014463 @default.
- W1991567315 cites W2011793611 @default.
- W1991567315 cites W2012753731 @default.
- W1991567315 cites W2013600728 @default.
- W1991567315 cites W2026286428 @default.
- W1991567315 cites W2027431505 @default.
- W1991567315 cites W2030539906 @default.
- W1991567315 cites W2030841140 @default.
- W1991567315 cites W2033620832 @default.
- W1991567315 cites W2034903738 @default.
- W1991567315 cites W2034991501 @default.
- W1991567315 cites W2035633424 @default.
- W1991567315 cites W2036400018 @default.
- W1991567315 cites W2036668937 @default.
- W1991567315 cites W2041828060 @default.
- W1991567315 cites W2043646561 @default.
- W1991567315 cites W2049271841 @default.
- W1991567315 cites W2052289384 @default.
- W1991567315 cites W2052821615 @default.
- W1991567315 cites W2056015818 @default.
- W1991567315 cites W2057093002 @default.
- W1991567315 cites W2057547754 @default.
- W1991567315 cites W2057949119 @default.
- W1991567315 cites W2060261232 @default.
- W1991567315 cites W2061842942 @default.
- W1991567315 cites W2064046171 @default.
- W1991567315 cites W2067502608 @default.
- W1991567315 cites W2068070596 @default.
- W1991567315 cites W2068905091 @default.
- W1991567315 cites W2070299944 @default.
- W1991567315 cites W2071535347 @default.
- W1991567315 cites W2074514832 @default.
- W1991567315 cites W2077734126 @default.
- W1991567315 cites W2078409757 @default.
- W1991567315 cites W2079977662 @default.
- W1991567315 cites W2085451822 @default.
- W1991567315 cites W2085544204 @default.
- W1991567315 cites W2087689803 @default.
- W1991567315 cites W2088167693 @default.
- W1991567315 cites W2089562522 @default.
- W1991567315 cites W2090616218 @default.
- W1991567315 cites W2091596100 @default.
- W1991567315 cites W2093969145 @default.
- W1991567315 cites W2094286960 @default.
- W1991567315 cites W2098284154 @default.
- W1991567315 cites W2105177764 @default.
- W1991567315 cites W2107011450 @default.
- W1991567315 cites W2109869487 @default.
- W1991567315 cites W2113022335 @default.
- W1991567315 cites W2114668953 @default.
- W1991567315 cites W2122210959 @default.
- W1991567315 cites W2128492772 @default.
- W1991567315 cites W2132128965 @default.
- W1991567315 cites W2143758133 @default.
- W1991567315 cites W2153509349 @default.
- W1991567315 cites W2155079447 @default.
- W1991567315 cites W2159515620 @default.
- W1991567315 cites W2164043498 @default.
- W1991567315 cites W2171915887 @default.
- W1991567315 cites W2314649643 @default.
- W1991567315 cites W4205222420 @default.
- W1991567315 cites W4235712266 @default.