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- W199157483 abstract "1. The variation of the d.c. electrical conductivity with temperature has been studied for a range of phospholipids in the polycrystalline solid condition and also in various mesomorphic states. The lipids examined include diacylphophatidylethanolamines, phophatidylcholines (lecithins), phosphatidylserines and phosphatidic acids. At the onset of each mesormophic phase, a change in the conduction parameters occurs. Fully saturated 1,2-diacylphosphatidylethanolamines possess 2 distinct mesormophic phases. At the transition temperature from crystalline to the first mesomorphic phase, the activation energy for conduction changes from approx. 2.0 eV to approx. 3.0 eV. At the second transition temperature the activation energy falls to about 0.8 eV. Phosphatidylcholines have a higher activation energy of approx. 3.5 eV in the crystalline state which decrease at the first transition temperature to 0.7–1.4 eV depending upon the degree of unsaturation in the hydrocarbon chain. 2. With the lecithins and phosphatidylserines an unusual conductivity effect is observed which might be associated with the formation of a cubic mesomorphic phase. 3. Correlation of the conductivity results with results obtained using other techniques, e.g. NMR spectroscopy, X-ray diffraction and thermal studies, suggest that the observed conductivity may be an intrinsic property associated with the polar end groups. 4. The specific resistance of the phospholipids is lowered by several orders of magnitude by the addition of small quantities of water. 5. These results are discussed with relevance to some biophysical problems of contemporary interest." @default.
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- W199157483 date "1967-11-01" @default.
- W199157483 modified "2023-09-26" @default.
- W199157483 title "Physical studies of phospholipids" @default.
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- W199157483 doi "https://doi.org/10.1016/0005-2736(67)90050-8" @default.
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