Matches in SemOpenAlex for { <https://semopenalex.org/work/W1991587675> ?p ?o ?g. }
Showing items 1 to 71 of
71
with 100 items per page.
- W1991587675 abstract "IT is well known that the addition of paramagnetic solutes to water brings about a marked reduction in the nuclear spin-lattice relaxation time of solvent protons1, the inverse of the relaxation time being linearly related to solute concentration according to the equation: where T1 and T0 are spin-lattice relaxation times in the presence and absence of added solute, respectively; α is a proportionality constant; μN is a parameter expressing the effectiveness of a particular solute in this phenomenon, sometimes called the ‘effective’ paramagnetic moment of the solute; C is the concentration of the solute. In the case of solutions of paramagnetic complex ions, the magnitude of the effect (that is, the value of μN) depends on the nature of the co-ordinated groups2. We find that the phenomenon enables the replacement of one ligand by another in solution to be followed with sufficient precision to form the basis for a method of determining the concentration of metal ions, and it is now suggested that this method of analysis should be widely applicable in cases where the addition of a complexing agent to the solution of a paramagnetic ion in solution causes the formation of a new complex ion of different μN and of high stability in solution. The analyses can conveniently be carried out by use of a low-resolution nuclear magnetic-resonance spectrometer." @default.
- W1991587675 created "2016-06-24" @default.
- W1991587675 creator A5051458407 @default.
- W1991587675 creator A5091809369 @default.
- W1991587675 date "1959-06-01" @default.
- W1991587675 modified "2023-09-23" @default.
- W1991587675 title "Magnetometric Titration: a New Method of Chemical Analysis" @default.
- W1991587675 cites W2054493015 @default.
- W1991587675 cites W2131904845 @default.
- W1991587675 doi "https://doi.org/10.1038/1831804a0" @default.
- W1991587675 hasPublicationYear "1959" @default.
- W1991587675 type Work @default.
- W1991587675 sameAs 1991587675 @default.
- W1991587675 citedByCount "1" @default.
- W1991587675 crossrefType "journal-article" @default.
- W1991587675 hasAuthorship W1991587675A5051458407 @default.
- W1991587675 hasAuthorship W1991587675A5091809369 @default.
- W1991587675 hasBestOaLocation W19915876751 @default.
- W1991587675 hasConcept C121332964 @default.
- W1991587675 hasConcept C124712363 @default.
- W1991587675 hasConcept C145148216 @default.
- W1991587675 hasConcept C147789679 @default.
- W1991587675 hasConcept C15744967 @default.
- W1991587675 hasConcept C159467904 @default.
- W1991587675 hasConcept C178790620 @default.
- W1991587675 hasConcept C184866935 @default.
- W1991587675 hasConcept C185592680 @default.
- W1991587675 hasConcept C199164860 @default.
- W1991587675 hasConcept C26873012 @default.
- W1991587675 hasConcept C2776029896 @default.
- W1991587675 hasConcept C77805123 @default.
- W1991587675 hasConceptScore W1991587675C121332964 @default.
- W1991587675 hasConceptScore W1991587675C124712363 @default.
- W1991587675 hasConceptScore W1991587675C145148216 @default.
- W1991587675 hasConceptScore W1991587675C147789679 @default.
- W1991587675 hasConceptScore W1991587675C15744967 @default.
- W1991587675 hasConceptScore W1991587675C159467904 @default.
- W1991587675 hasConceptScore W1991587675C178790620 @default.
- W1991587675 hasConceptScore W1991587675C184866935 @default.
- W1991587675 hasConceptScore W1991587675C185592680 @default.
- W1991587675 hasConceptScore W1991587675C199164860 @default.
- W1991587675 hasConceptScore W1991587675C26873012 @default.
- W1991587675 hasConceptScore W1991587675C2776029896 @default.
- W1991587675 hasConceptScore W1991587675C77805123 @default.
- W1991587675 hasLocation W19915876751 @default.
- W1991587675 hasOpenAccess W1991587675 @default.
- W1991587675 hasPrimaryLocation W19915876751 @default.
- W1991587675 hasRelatedWork W1585550871 @default.
- W1991587675 hasRelatedWork W1590246329 @default.
- W1991587675 hasRelatedWork W1966122537 @default.
- W1991587675 hasRelatedWork W1998480277 @default.
- W1991587675 hasRelatedWork W2017997320 @default.
- W1991587675 hasRelatedWork W2020879056 @default.
- W1991587675 hasRelatedWork W2044329532 @default.
- W1991587675 hasRelatedWork W2047863765 @default.
- W1991587675 hasRelatedWork W2050901227 @default.
- W1991587675 hasRelatedWork W2069907941 @default.
- W1991587675 hasRelatedWork W2070958231 @default.
- W1991587675 hasRelatedWork W2072668146 @default.
- W1991587675 hasRelatedWork W2076959355 @default.
- W1991587675 hasRelatedWork W2081821339 @default.
- W1991587675 hasRelatedWork W2102979713 @default.
- W1991587675 hasRelatedWork W2106240452 @default.
- W1991587675 hasRelatedWork W2138754186 @default.
- W1991587675 hasRelatedWork W2150877322 @default.
- W1991587675 hasRelatedWork W3205824981 @default.
- W1991587675 hasRelatedWork W34323014 @default.
- W1991587675 isParatext "false" @default.
- W1991587675 isRetracted "false" @default.
- W1991587675 magId "1991587675" @default.
- W1991587675 workType "article" @default.