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• W1991591444 abstract "The reduction of Cd(II) to Cd(Hg) has been studied by means of demodulation voltammetry in a wide potential range and at various water activities using NaClO4 as the base electrolyte. From this study it is concluded that the reduction proceeds according to: (i) fast loss of 12.5 water molecules in a preceding equilibrium; (ii) a slow “chemical” step, which is not a desolvation; (iii) slow transfer of the first electron; (iv) fast loss of four water molecules; (v) slow transfer of the second electron; and (vi) fast loss of the remaining nine water molecules. These results and the values of the rate constants obtained are compared with results obtained earlier on the reduction of Zn(II)." @default.
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• W1991591444 date "1989-02-01" @default.
• W1991591444 modified "2023-10-18" @default.
• W1991591444 title "The mechanism of the reduction of cadmium ions at a dropping mercury electrode from NaClO4 base electrolyte solutions with varied water activity" @default.
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• W1991591444 doi "https://doi.org/10.1016/0022-0728(89)80051-8" @default.
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