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- W1991623497 abstract "Proton NMR second moment and spin—lattice relaxation times T 1 and T 1p have been studied for polycrystalline guanidinium hexachloroantimonate C(NH2)3SbCl6 in a wide temperature range. A dynamic inequivalence of two cations has been detected in spite of their crystal-lographical equivalence. Activation parameters for C3 reorientation and self-diffusion of the more mobile cation have been determined. It was shown that the para–ferroelastic phase transition at 351 K is connected with abrupt changes in the dynamics of the two cations. The weaker, second-order transition at 265 K is thought to be related to a change in the dynamics of one of the cations." @default.
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- W1991623497 date "2002-06-20" @default.
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- W1991623497 title "NMR study of guanidinium cation dynamics in C(NH2)3SbCl6" @default.
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- W1991623497 doi "https://doi.org/10.1080/00268970210127951" @default.
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