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• W1991649982 endingPage "9626" @default.
• W1991649982 startingPage "9617" @default.
• W1991649982 abstract "Two Cu(II) coordination complexes {[Cu(ces)(H(2)O)(2)](H(2)O)(0.5)}(n) (1) and [Cu(15)(dhs)(6)(OH)(6)(H(2)O)(10)](H(2)O)(20) (2) have been synthesized from cis-epoxysuccinic acid (cis-H(2)ces) and Cu(II) perchlorate under different pH conditions (ces = cis-epoxysuccinate and dhs = 2,3-dihydroxysuccinate), and fully characterized by IR spectra, elemental analyses, as well as single crystal and powder X-ray diffraction techniques. Notably, when the reaction was performed at pH above about 7.4, a one-dimensional (1-D) helical chain complex 1 is formed, whereas a neutral isolated Cu(15) nanocluster 2 is generated when the pH value is decreased to the range of about 6.6-7.3, being concomitant with in situ S(N)2 ring-cleavage reaction of cis-H(2)ces to form (2S,3S)- and (2R,3R)-H(4)dhs. Further, extended supramolecular architectures are constructed via secondary interactions in both structures. The magnetic properties of 1 and 2 have also been studied in detail, showing that 1 is an antiferromagnetic helical chain of S = 1/2 spins and 2 possesses an S = 3/2 spin ground state." @default.
• W1991649982 created "2016-06-24" @default.
• W1991649982 creator A5006121200 @default.
• W1991649982 creator A5009324355 @default.
• W1991649982 creator A5014277040 @default.
• W1991649982 creator A5039837606 @default.
• W1991649982 creator A5064468499 @default.
• W1991649982 creator A5073412799 @default.
• W1991649982 date "2010-09-20" @default.
• W1991649982 modified "2023-09-28" @default.
• W1991649982 title "From Infinite One-Dimensional Helix to Discrete Cu^II₁₅ Cluster along with in Situ S_N2 Ring-Cleavage of <i>cis</i>-Epoxysuccinic Acid: pH-Controlled Assemblies, Crystal Structures, and Properties" @default.
• W1991649982 cites W1628423641 @default.
• W1991649982 cites W1691765861 @default.
• W1991649982 cites W1820345752 @default.
• W1991649982 cites W1842151646 @default.
• W1991649982 cites W1882246431 @default.
• W1991649982 cites W1883086253 @default.
• W1991649982 cites W1905819222 @default.
• W1991649982 cites W1965721735 @default.
• W1991649982 cites W1969837415 @default.
• W1991649982 cites W1970092751 @default.
• W1991649982 cites W1970993202 @default.
• W1991649982 cites W1971136591 @default.
• W1991649982 cites W1972646318 @default.
• W1991649982 cites W1975744445 @default.
• W1991649982 cites W1978506712 @default.
• W1991649982 cites W1978659336 @default.
• W1991649982 cites W1979191271 @default.
• W1991649982 cites W1979433790 @default.
• W1991649982 cites W1979728293 @default.
• W1991649982 cites W1981144641 @default.
• W1991649982 cites W1983815225 @default.
• W1991649982 cites W1985161231 @default.
• W1991649982 cites W1985568020 @default.
• W1991649982 cites W1987672211 @default.
• W1991649982 cites W1991057004 @default.
• W1991649982 cites W1991479303 @default.
• W1991649982 cites W1991635410 @default.
• W1991649982 cites W1994342755 @default.
• W1991649982 cites W1994369789 @default.
• W1991649982 cites W1995437902 @default.
• W1991649982 cites W1995911177 @default.
• W1991649982 cites W1996074917 @default.
• W1991649982 cites W1997723317 @default.
• W1991649982 cites W1998612672 @default.
• W1991649982 cites W1999937609 @default.
• W1991649982 cites W2001046252 @default.
• W1991649982 cites W2002954023 @default.
• W1991649982 cites W2004041048 @default.
• W1991649982 cites W2007932100 @default.
• W1991649982 cites W2008151531 @default.
• W1991649982 cites W2008940856 @default.
• W1991649982 cites W2009799156 @default.
• W1991649982 cites W2010523179 @default.
• W1991649982 cites W2010697328 @default.
• W1991649982 cites W2012763297 @default.
• W1991649982 cites W2014056753 @default.
• W1991649982 cites W2017203557 @default.
• W1991649982 cites W2017935501 @default.
• W1991649982 cites W2022167379 @default.
• W1991649982 cites W2023154437 @default.
• W1991649982 cites W2023633637 @default.
• W1991649982 cites W2028384567 @default.
• W1991649982 cites W2029671842 @default.
• W1991649982 cites W2030637195 @default.
• W1991649982 cites W2031534602 @default.
• W1991649982 cites W2031616058 @default.
• W1991649982 cites W2032642939 @default.
• W1991649982 cites W2034370062 @default.
• W1991649982 cites W2039691813 @default.
• W1991649982 cites W2047072028 @default.
• W1991649982 cites W2047198066 @default.
• W1991649982 cites W2047564046 @default.
• W1991649982 cites W2051143426 @default.
• W1991649982 cites W2051798377 @default.
• W1991649982 cites W2052053534 @default.
• W1991649982 cites W2053601701 @default.
• W1991649982 cites W2055949694 @default.
• W1991649982 cites W2056233116 @default.
• W1991649982 cites W2056404544 @default.
• W1991649982 cites W2057551599 @default.
• W1991649982 cites W2057958821 @default.
• W1991649982 cites W2060391646 @default.
• W1991649982 cites W2061239174 @default.
• W1991649982 cites W2061316676 @default.
• W1991649982 cites W2061551249 @default.
• W1991649982 cites W2062723086 @default.
• W1991649982 cites W2064049880 @default.
• W1991649982 cites W2070989955 @default.
• W1991649982 cites W2072972507 @default.
• W1991649982 cites W2073549495 @default.
• W1991649982 cites W2076575722 @default.
• W1991649982 cites W2077099196 @default.
• W1991649982 cites W2078413842 @default.
• W1991649982 cites W2078740295 @default.
• W1991649982 cites W2080503488 @default.
• W1991649982 cites W2082481002 @default.
• W1991649982 cites W2084615665 @default.

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