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- W1991654310 abstract "The structure of several monoclinic crystals of true NASICON-type materials Na1+xZr2P3−xSixO12 are examined at room temperature and 400 K. Two types of ion-ion correlation are observed. Type I corresponds to an ideal composition x=2; it is closely related to the monoclinic modification of α-Na3Sc2(PO4)3; ferroelectric-type order with four kinds of occupied Na sites: Na(1), regular Na(2)′, displaced Na(3)′ and mid-Na. Disordering resulting from both P/Si substitution and from nonstoichiometry screening of the long-range order leads to a residual occupancy of the regular Na(1) site. Type II, present for x≥2.25, corresponds to an anti-ferroelectric local order with three types of occupied Na sites: Na(1), regular Na(3)′ and mid-Na. The Na(2)′ site is empty. There is again only a residual occupancy of the Na(1) site. The existence of an interstitial mid-Na site establishes that the ion-ion correlations provide an essential part to the site potentials and that the driving mechanism for the phase transition is principally due to the modification of the host-lattice polarization by the conducting ions." @default.
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- W1991654310 date "1988-09-01" @default.
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- W1991654310 title "The monoclinic phase of true NASICON: Structure, correlations and transition" @default.
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- W1991654310 doi "https://doi.org/10.1016/s0167-2738(88)80077-8" @default.
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