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- W1991666089 abstract "A series of well-defined amphiphilic graft copolymers consisting of a hydrophobic poly(tert-butyl acrylate) (PtBA) backbone and hydrophilic poly(N-vinylcaprolactam) (PNVCL) side chains were synthesized via the combination of reversible addition–fragmentation chain transfer (RAFT) polymerization, atom transfer radical polymerization (ATRP), and the grafting-from strategy without any polymeric functional transformation. RAFT homopolymerization of tert-butyl 2-((2-bromopropanoyloxy)methyl)acrylate (tBBPMA) was first performed to give a well-defined Br-containing PtBBPMA backbone with a low polydispersity (Mw/Mn = 1.22). PNVCL side chains were grown from the backbone via straightforward ATRP of N-vinylcaprolactam using CuBr/Me6Cyclam as the catalytic system in 1,4-dioxane to afford the target PtBA-g-PNVCL amphiphilic graft copolymers with narrow molecular weight distributions (Mw/Mn ≤ 1.32). The self-assembly behavior of these graft copolymers in aqueous media was studied by fluorescence spectroscopy and transmission electron microscopy (TEM), and furthermore, their thermo-responsive behavior was investigated by UV-vis and dynamic light scattering (DLS). Finally, the hydrophobic PtBA backbone was selectively hydrolyzed into a hydrophilic PAA backbone without affecting PNVCL side chains in the acidic environment to provide PAA-g-PNVCL graft copolymers." @default.
- W1991666089 created "2016-06-24" @default.
- W1991666089 creator A5007882381 @default.
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- W1991666089 date "2013-01-01" @default.
- W1991666089 modified "2023-09-23" @default.
- W1991666089 title "A novel poly(N-vinylcaprolactam)-based well-defined amphiphilic graft copolymer synthesized by successive RAFT and ATRP" @default.
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- W1991666089 doi "https://doi.org/10.1039/c2py20933k" @default.
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