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• W1991788640 abstract "The tip of a scanning tunneling microscope (STM) can be used to dehydrogenate freely-diffusing tetrathienoanthracene (TTA) molecules on Cu(111), trapping the molecules into metal-coordinated oligomeric structures. The process proceeds at bias voltages above ~3 V and produces organometallic structures identical to those resulting from the thermally-activated cross-coupling of a halogenated analogue. The process appears to be substrate dependent: no oligomerization was observed on Ag(111) or HOPG. This approach demonstrates the possibility of controlled synthesis and nanoscale patterning of 2D oligomer structures on selected surfaces." @default.
• W1991788640 created "2016-06-24" @default.
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• W1991788640 date "2014-01-01" @default.
• W1991788640 modified "2023-09-30" @default.
• W1991788640 title "Tip-induced C–H activation and oligomerization of thienoanthracenes" @default.
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• W1991788640 doi "https://doi.org/10.1039/c4cc03719g" @default.
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