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• W1991821085 abstract "An investigation of the crystal structures of 3346 silicon- and 718 germanium-containing compounds was carried out with a geometrical–topological analysis. The descriptors of inter- and intramolecular contacts A ... D are given. Information on the descriptors of T — A ... D (where T = leaving group) interactions in terms of a stereoatomic model of crystal structures was described as being helpful in modelling S N 2 reactions. It was established that the formation of multiple intermolecular contacts in crystal structures is unfavorable. The dependence of the descriptors of intermolecular contacts T — A ...D was studied as a function of the nature of T (leaving group in substitution reactions) and D (nucleophile atom or group of atoms) groups, and the coordination number of an A atom. The constancy of the T — A and A ... D bond-order sum in crystal structures was demonstrated." @default.
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• W1991821085 date "2008-07-10" @default.
• W1991821085 modified "2023-10-16" @default.
• W1991821085 title "Special features of intermolecular bonding<i>A</i>...<i>D</i>(<i>A</i>= Si, Ge and<i>D</i>= nucleophile) in crystal structures" @default.
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• W1991821085 doi "https://doi.org/10.1107/s0108768108016170" @default.
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