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- W1991833508 abstract "Oxonium tris(2-aminobenzenecarboxylato) dioxouranium (VI) monohydrate crystals contain monomeric molecules composed of a UO2 group (UO 1.755 Å mean; 178.3°) and six oxygen atoms in the equatorial plane (UO mean 2.456 Å) donated by three bidentate carboxylic groups of anthranilic acid molecules. The coordination polyhedron is thus a hexagonal bipyramid involving solely O-coordination. Monoaquobis(2-pyrazinecarboxylato)dioxouranium(VI) dihydrate complex molecules are monomeric. The UO2 group (UO mean 1.770 Å, 179.1°) is surrounded in the equatorial plane by two oxygen atoms (UO mean 2.318 Å), two nitrogen atoms (U mean 2.583 Å) donated by pyrazinic acid molecules, and one oxygen atom from a water molecule (UO 2.405 Å). The coordination polyhedron around the U atom is thus a pentagonal bipyramid and reflects the propensity for ring N atoms to coordinate with uranyl ions. In the crystal, molecules of both title compounds are held together by systems of hydrogen bonds." @default.
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- W1991833508 date "1996-07-01" @default.
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- W1991833508 title "The roles of N- and O-coordination in the crystal and molecular structures of uranyl complexes with anthranilic and pyrazinic acids" @default.
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- W1991833508 doi "https://doi.org/10.1016/0020-1693(96)05012-8" @default.
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