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• W1991841241 abstract "The primary products of the reaction of lithium atoms and carbon tetrachloride in solid argon at 15°K are lithium chloride and the trichloromethyl radical, which are identified by infrared spectral studies. Natural chlorine isotopes, carbon 13 and bromine substitution, and loss of CCl3 absorptions with attendant growth of absorptions due to C2Cl6 on sample warming verify the molecular identity. Assignments to the carbon–chlorine stretching vibrations ν1 = 674 and ν3 = 898 cm−1 are supported by normal coordinate calculations, and the weak bending modes ν2 and ν4 were not detected. The stretching force constants Fτ = 3.83 mdyn / Å and Fττ = 0.43 mdyn / Å are compared with those of other chlorocarbons and BCl3 This comparison supports proposed resonance stabilization of the trichloromethyl radical." @default.
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• W1991841241 date "1968-02-01" @default.
• W1991841241 modified "2023-10-11" @default.
• W1991841241 title "Infrared Spectrum of the Trichloromethyl Radical in Solid Argon" @default.
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• W1991841241 doi "https://doi.org/10.1063/1.1668852" @default.
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