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- W1991852212 abstract "The compositional dependence of the thermal properties of SbxSe100−x melt quenched glasses (0.01 < x < 25 at.%) has been studied. Modulated temperature differential scanning calorimetry technique has been applied to determine the thermal properties of Se-rich SbxSe100−x chalcogenide glasses in the glass transition and crystallization regions. The reversing and non-reversing heat flows through the glass transformations were measured during both heating and cooling scans. Tg (glass transition), ΔHg (relaxation enthalpy), Cp (specific heat capacity), ΔCp (change in Cp at Tg), ΔHc (crystallization enthalpy), Tp (peak crystallization rate temperature) and Tc (crystallization onset temperature) which determine the thermal events in the glass were calculated from the experimental curves. Some of the structurally controlled parameters such as Tg, Cp, and Tc − Tg reveal local extrema when the Sb–Se glass system reaches 1 at.% Sb and 15 at.% Sb approximate concentrations, where the glass forming ability was also maximal. We discuss the results in terms of possible dimensional structural changes, `size effect' and local stoichiometry." @default.
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- W1991852212 date "1999-06-01" @default.
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- W1991852212 title "Thermal properties of SbxSe100−x glasses studied by modulated temperature differential scanning calorimetry" @default.
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- W1991852212 doi "https://doi.org/10.1016/s0022-3093(99)00100-3" @default.
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