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- W1991895065 abstract "The first stability constants (log β1) of the copper(II) complex of glycine in water and in 13 water + alcohol (isopropanol, tert-butanol, 1,2-propylene glycol and glycerol) solvents have been determined at 25°C and an ionic strength of 0.10, from pH and pCu measurements of cells containing copper(II) ion selective electrode. It has been shown that as the proportion of the alcohol increases, the stability constants become increasing positive in all of the mixed solvents examined. An almost linear relation between log β1 and the mole fraction of alcohol was found for the complex in aqueous solutions of isopropanol, tert-butanol and glycerol. The response of the copper(II) ion selective electrode in water and in water + alcohol mixed solvents was also investigated. The advantages of using an ion selective electrode to determine the stability constants in mixed solvents are discussed." @default.
- W1991895065 created "2016-06-24" @default.
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- W1991895065 date "1995-03-01" @default.
- W1991895065 modified "2023-09-25" @default.
- W1991895065 title "Determination of stability constants of copper(II) complex of glycine in water + alcohol mixed solvents with ion selective electrode technique" @default.
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- W1991895065 doi "https://doi.org/10.1016/0039-9140(95)01394-q" @default.
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