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- W1991900132 abstract "The absolute configuration of stendomycidine (I), a constituent of the peptide antibiotic stendomycin, was determined. Optical rotatory dispersion (ORD) measurements showed the configuration at the α-carbon atom to be that of an L-amino acid. Degradation of stendomycidine with N-bromosuccinimide yielded 2-methylimino-3-methyl-hexahydropyrimidine-4-carboxylic acid (II), a compound with only one center of asymmetry. A comparison of the ORD spectrum of compound II with that of 2-imino-hexahydropyrimidine-4-carboxylic acid (III), prepared from authentic L-α, γ-diaminobutyric acid, showed that the second center of asymmetry also has the L-configuration. Hence, the L-erythro configuration was assigned to stendomycidine. Comparison of the nmr spectra of stendomycidine and capreomycidine added some additional support to the above assignment." @default.
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- W1991900132 title "THE CONFIGURATION OF STENDOMYCIDINE" @default.
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- W1991900132 doi "https://doi.org/10.7164/antibiotics.23.120" @default.
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