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- W1991934999 abstract "Experiments were carried out using rapid-quench hydrothermal techniques to determine the solubility of bunsenite (NiO) in supercritical H2O-NaCl-NiCl2 solutions in the range 550 to 750°C, at 2 kbar. The solubility of NiO was enhanced by the formation of complexes of higher stoichiometry than NiCl20 in the presence of increasing concentrations of aqueous NaCl. The results are consistent with the formation of the NiCl3− complex in the fluid over the entire temperature range, as a result of the reaction NiCl20(aq) + Cl−(aq) = NiCl3−(aq). The variation in values of the equilibrium constant for the above reaction is given by logKeq = 3.40(±0.83) − 2365 (±758)/T(°K). Despite the increase in solubility that results in the NaCl-bearing system, nickel should still remain a relatively immobile element, as compared to Ca, Mg, Fe and Mn, in supercritical aqueous Cl-bearing fluids, provided the activity of nickel in the coexisting solid mineral assemblage is not unusually high." @default.
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- W1991934999 date "1989-05-01" @default.
- W1991934999 modified "2023-09-27" @default.
- W1991934999 title "The effect of NaCl on bunsenite solubility and Ni-complexing in supercritical aqueous fluids" @default.
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- W1991934999 doi "https://doi.org/10.1016/0016-7037(89)90204-4" @default.
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