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- W1992003529 abstract "A novel potential bidentate sulfur ligand, K 2 [S 2 CNHCOCH 2 CN] and its complexes with first row divalent transition metal ions of the type, M(phen)L, [M = Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Pd(II), L = S 2 CNHCOCH 2 CN and phen = 1,10-phenanthroline] have been synthesised and characterised. On the basis of IR and 1 H NMR an enol form is found in the case of ligand and its complexes in the solid state whereas the complexes exist predominantly in the keto form in solution. Electronic spectra and magnetic measurement data indicate that the Ni(II), Cu(II) and Pd(II) complexes have a square-planar geometry but the others have a distorted-tetrahedral structure." @default.
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- W1992003529 date "2006-09-01" @default.
- W1992003529 modified "2023-10-16" @default.
- W1992003529 title "Unique Keto-Enol Tautomerism in Transition Metal Complexes of Cyanoimidodithiocarbonate" @default.
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