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- W1992014759 abstract "Abstract Postsynthetic modification of [Cu 2 (mand) 2 (hmt)] (mand=mandelic acid, hmt=hexamethylenetetramine) with a chiral, dimeric chromium(III)–salen complex led to a robust structure. Characterization of this new material showed that it perfectly preserved the textural and structural properties of the parent metal–organic framework (MOF). Although epoxidation of trans ‐methyl cinnamate with hydrogen peroxide led to copper leaching of 2–3 %, experiments performed with N ‐methylmorpholine‐ N ‐oxide indicated no leaching, even after 72 h of exposure. The obtained chiral MOF is an effective catalyst for the enantioselective epoxidation of trans ‐methyl cinnamate and leads to (2 R ,3 S )‐phenylglycidate with a high enantiomeric excess at room temperature." @default.
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- W1992014759 date "2013-04-05" @default.
- W1992014759 modified "2023-10-17" @default.
- W1992014759 title "Postsynthetic Modification of a Metal-Organic Framework (MOF) Structure for Enantioselective Catalytic Epoxidation" @default.
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- W1992014759 doi "https://doi.org/10.1002/cplu.201300076" @default.
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