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- W1992017852 abstract "The reaction of 1,2,3-triphenylphosphirene with [H 2 Os 3 -(CO) 10 ] leads to the title compound, [Os 3 (CO) 9 {(C 6 H 5 )3-C 2 PO}], which displays an open Os 3 (CO) 9 cluster [Os-Os 2.703(1) and 2.867(2)A, and Os-Os-Os 124.24 (4)°] This moiety is μ3,n 3 -bonded to a phosphirene ligand with a cleaved P-C bond, PhC-C(Ph)P. An O atom was incorporated into the molecule resulting in an unusual five-membered metallocycle, Os-C-C-P-O, with distances Os-C 2.10(1), C-C 1.46(2), C-P 1.76(1), P-O 1.628(9) and O-Os 2.136(9)A. This ring makes a dihedral angle of 57.3 (2)° with the plane of the metal atoms." @default.
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- W1992017852 date "1997-03-15" @default.
- W1992017852 modified "2023-09-23" @default.
- W1992017852 title "Nonacarbonyl[μ<sub>3</sub>-(1,2-diphenylethyl)phenylphosphinito]triosmium(2<i>Os</i>—<i>Os</i>)" @default.
- W1992017852 doi "https://doi.org/10.1107/s0108270196008219" @default.
- W1992017852 hasPublicationYear "1997" @default.
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