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- W1992036651 abstract "In order to study the structural limits in the design of molecular motors, a tert-butyl substituted analogue was prepared. The unexpected photochemical and thermal isomerisation processes and the stereochemistry of new overcrowded alkene 5 are described. The bis tert-butyl substituted alkenes were synthesised in a five-step sequence with an overall yield of 7.5%. Structural assignments of the isomers based on experimental data were supported by calculations of all four isomers of the alkene. X-Ray crystal analysis showed a strongly twisted alkene (torsion angle 39°) for a less stable photochemically generated cis-isomer." @default.
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- W1992036651 date "2007-01-01" @default.
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- W1992036651 title "Synthesis, stereochemistry, and photochemical and thermal behaviour of bis-tert-butyl substituted overcrowded alkenes" @default.
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- W1992036651 doi "https://doi.org/10.1039/b611070c" @default.
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