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- W1992067421 abstract "The volatilization of iridium in dry oxygen at a pressure of 1 atm was investigated between 1435 and 1628 K by means of the transpiration method. The temperature dependence of iridium transport above 1500 K was different from that at lower temperatures. The results were interpreted in terms of the following heterogeneous reactions: Ir(s) + 32O2(g) = IrO3(g)2Ir(s) + 32O2(g) = Ir2O3(g)log PIro3=−993.4±279T − (2.297 ± 0.190)log PIr2O3=−15965±1954T+(5.934±1.250) where pIro3 and Pr2O3 are in atmospheres and T is in kelvins. From these measured pressures the free enthalpies of formation of IrO3(g) and Ir2O3(g) respectively were evaluated as ΔGfo {IrO3(g)} = (4550 ± 1280) + (10.5 ± 0.9)TΔGfo {Ir2O3(g)} = (72600 ± 8900) − (27.2 ± 5.7)T where ΔGfo is in calories per mole." @default.
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- W1992067421 date "1981-07-01" @default.
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- W1992067421 title "The pressure of iridium oxides over iridium at high temperatures in 1 atm of dry oxygen" @default.
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- W1992067421 doi "https://doi.org/10.1016/0022-5088(81)90162-4" @default.
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