FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1992068462> ?p ?o ?g. }

• W1992068462 endingPage "97" @default.
• W1992068462 startingPage "83" @default.
• W1992068462 abstract "Over decades, information about the rheological properties of the condensed monolayer phases has been obtained by introduction of a two-dimensional compressibility which is defined on the basis of the surface pressure-molecular area (Pi-A) features of the monolayer. Since the last decade, fundamental progress was attained in the experimental determination of the main characteristics of Langmuir monolayers in microscopic and molecular scale. Already smallest changes in the molecular structure of the amphiphile can result in changes in the molecular arrangement in the monolayer and thus, in changes of the main characteristics of the monolayer such as, the surface pressure-area per molecule (Pi-A) isotherms, the shape and texture of the condensed phase domains and the two-dimensional lattice structure. As the classical equations of state allowed only characterisation of the fluid (gaseous, liquid-expanded) state, thermodynamically based equations of state, which consider also the aggregation of the monolayer material to the condensed phase, have been developed. The present review focuses particularly to amphiphilic monolayers, the Pi-A isotherms of which indicate the existence of two condensed phases. For this case, the experimental results of the differences in the structure features and phase properties are discussed. The generalisation of the equation of state for Langmuir monolayers developed for the case that one, two or more phase transitions in the monolayer take place, is in agreement with the experimental results that the two-dimensional compressibility of the condensed phases undergoes a jump at the phase transition, whereas the compressibility is proportional to the surface pressure within one of the condensed phases. An example is presented which explains the procedure of the theoretical analysis of Pi-A isotherms indicating the existence of two condensed phases. An element of the procedure is the application of the general principle that the behaviour of any thermodynamic system is determined by the stability condition. An interesting anisotropy of the compressibility is revealed by GIXD studies of the S-phase of octadecanol monolayers. However, similar studies performed close to the LS-S-phase transition would result in a thermodynamically impossible negative compressibility. Close to this phase transition, the compressibility cannot be determined from the positions of the maxima because the monolayer is in a disordered state attributed to elastic distortions by fluctuations with the structure of the new phase in the surrounding matrix without destroying the quasi-long-range positional order." @default.
• W1992068462 created "2016-06-24" @default.
• W1992068462 creator A5017976089 @default.
• W1992068462 creator A5058449762 @default.
• W1992068462 date "2006-11-01" @default.
• W1992068462 modified "2023-09-27" @default.
• W1992068462 title "Progress in characterization of Langmuir monolayers by consideration of compressibility" @default.
• W1992068462 cites W1963605076 @default.
• W1992068462 cites W1968182680 @default.
• W1992068462 cites W1968719938 @default.
• W1992068462 cites W1978669137 @default.
• W1992068462 cites W1980037098 @default.
• W1992068462 cites W1983247736 @default.
• W1992068462 cites W1987731736 @default.
• W1992068462 cites W1995918488 @default.
• W1992068462 cites W2007907764 @default.
• W1992068462 cites W2008689758 @default.
• W1992068462 cites W2015595640 @default.
• W1992068462 cites W2019115557 @default.
• W1992068462 cites W2019535309 @default.
• W1992068462 cites W2019620219 @default.
• W1992068462 cites W2019627808 @default.
• W1992068462 cites W2023363879 @default.
• W1992068462 cites W2028587947 @default.
• W1992068462 cites W2029747592 @default.
• W1992068462 cites W2031474880 @default.
• W1992068462 cites W2032364357 @default.
• W1992068462 cites W2034129527 @default.
• W1992068462 cites W2036886876 @default.
• W1992068462 cites W2041009248 @default.
• W1992068462 cites W2042786341 @default.
• W1992068462 cites W2044922212 @default.
• W1992068462 cites W2049158215 @default.
• W1992068462 cites W2049918505 @default.
• W1992068462 cites W2050313387 @default.
• W1992068462 cites W2055093309 @default.
• W1992068462 cites W2063298409 @default.
• W1992068462 cites W2065157197 @default.
• W1992068462 cites W2067984340 @default.
• W1992068462 cites W2073286791 @default.
• W1992068462 cites W2073483134 @default.
• W1992068462 cites W2081468885 @default.
• W1992068462 cites W2081545495 @default.
• W1992068462 cites W2082676026 @default.
• W1992068462 cites W2082767891 @default.
• W1992068462 cites W2083524081 @default.
• W1992068462 cites W2088055248 @default.
• W1992068462 cites W2088167544 @default.
• W1992068462 cites W2090426221 @default.
• W1992068462 cites W2091401462 @default.
• W1992068462 cites W2092457626 @default.
• W1992068462 cites W2116893205 @default.
• W1992068462 cites W2118587471 @default.
• W1992068462 cites W2611783303 @default.
• W1992068462 doi "https://doi.org/10.1016/j.cis.2006.11.006" @default.
• W1992068462 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17208192" @default.
• W1992068462 hasPublicationYear "2006" @default.
• W1992068462 type Work @default.
• W1992068462 sameAs 1992068462 @default.
• W1992068462 citedByCount "91" @default.
• W1992068462 countsByYear W19920684622012 @default.
• W1992068462 countsByYear W19920684622013 @default.
• W1992068462 countsByYear W19920684622014 @default.
• W1992068462 countsByYear W19920684622015 @default.
• W1992068462 countsByYear W19920684622016 @default.
• W1992068462 countsByYear W19920684622017 @default.
• W1992068462 countsByYear W19920684622018 @default.
• W1992068462 countsByYear W19920684622019 @default.
• W1992068462 countsByYear W19920684622020 @default.
• W1992068462 countsByYear W19920684622021 @default.
• W1992068462 countsByYear W19920684622022 @default.
• W1992068462 countsByYear W19920684622023 @default.
• W1992068462 crossrefType "journal-article" @default.
• W1992068462 hasAuthorship W1992068462A5017976089 @default.
• W1992068462 hasAuthorship W1992068462A5058449762 @default.
• W1992068462 hasConcept C101677414 @default.
• W1992068462 hasConcept C115958267 @default.
• W1992068462 hasConcept C121332964 @default.
• W1992068462 hasConcept C147789679 @default.
• W1992068462 hasConcept C149288129 @default.
• W1992068462 hasConcept C150394285 @default.
• W1992068462 hasConcept C159467904 @default.
• W1992068462 hasConcept C171250308 @default.
• W1992068462 hasConcept C178790620 @default.
• W1992068462 hasConcept C185592680 @default.
• W1992068462 hasConcept C192562407 @default.
• W1992068462 hasConcept C44280652 @default.
• W1992068462 hasConcept C53810900 @default.
• W1992068462 hasConcept C57879066 @default.
• W1992068462 hasConcept C7070889 @default.
• W1992068462 hasConcept C84655787 @default.
• W1992068462 hasConcept C97355855 @default.
• W1992068462 hasConceptScore W1992068462C101677414 @default.
• W1992068462 hasConceptScore W1992068462C115958267 @default.
• W1992068462 hasConceptScore W1992068462C121332964 @default.
• W1992068462 hasConceptScore W1992068462C147789679 @default.
• W1992068462 hasConceptScore W1992068462C149288129 @default.
• W1992068462 hasConceptScore W1992068462C150394285 @default.

• next