Matches in SemOpenAlex for { <https://semopenalex.org/work/W1992071814> ?p ?o ?g. }
Showing items 1 to 66 of
66
with 100 items per page.
- W1992071814 endingPage "2399" @default.
- W1992071814 startingPage "2396" @default.
- W1992071814 abstract "Rapid freezing of metal–ammonia solutions, containing added salt to inhibit solvent crystallisation, gave blue solids whose e.s.r. spectra were generally characterised by three distinct features: (i) an intense narrow, line with g 1·9992 and ΔHMS 0·035 G; (ii) a broad singlet associated with colloidal metal particles; and (iii) a triplet probably associated with 14N nuclei.The narrow line is thought to have considerable significance since there must be rapid effective nuclear exchange in order that the expected hyperfine coupling to 1H and 14N nuclei of the solvent be averaged almost to zero. We suggest that electron transfer between one-(e1) and two-electron (e2) centres: e1+e2⇌e2+e1, is rapid, even at 77 K, and that this leads to effective nuclear averaging without limiting the spin liftimes. Possible assignments for the triplet are discussed." @default.
- W1992071814 created "2016-06-24" @default.
- W1992071814 creator A5009188687 @default.
- W1992071814 creator A5035274055 @default.
- W1992071814 creator A5067975595 @default.
- W1992071814 creator A5083652293 @default.
- W1992071814 date "1971-01-01" @default.
- W1992071814 modified "2023-09-25" @default.
- W1992071814 title "Unstable intermediates. Part XCIX. Solvated electrons in solid metal–ammonia solutions" @default.
- W1992071814 doi "https://doi.org/10.1039/j19710002396" @default.
- W1992071814 hasPublicationYear "1971" @default.
- W1992071814 type Work @default.
- W1992071814 sameAs 1992071814 @default.
- W1992071814 citedByCount "2" @default.
- W1992071814 crossrefType "journal-article" @default.
- W1992071814 hasAuthorship W1992071814A5009188687 @default.
- W1992071814 hasAuthorship W1992071814A5035274055 @default.
- W1992071814 hasAuthorship W1992071814A5067975595 @default.
- W1992071814 hasAuthorship W1992071814A5083652293 @default.
- W1992071814 hasConcept C121332964 @default.
- W1992071814 hasConcept C139066938 @default.
- W1992071814 hasConcept C147120987 @default.
- W1992071814 hasConcept C159467904 @default.
- W1992071814 hasConcept C178790620 @default.
- W1992071814 hasConcept C179104552 @default.
- W1992071814 hasConcept C185544564 @default.
- W1992071814 hasConcept C185592680 @default.
- W1992071814 hasConcept C2776382133 @default.
- W1992071814 hasConcept C42296456 @default.
- W1992071814 hasConcept C544153396 @default.
- W1992071814 hasConcept C66887884 @default.
- W1992071814 hasConcept C75473681 @default.
- W1992071814 hasConceptScore W1992071814C121332964 @default.
- W1992071814 hasConceptScore W1992071814C139066938 @default.
- W1992071814 hasConceptScore W1992071814C147120987 @default.
- W1992071814 hasConceptScore W1992071814C159467904 @default.
- W1992071814 hasConceptScore W1992071814C178790620 @default.
- W1992071814 hasConceptScore W1992071814C179104552 @default.
- W1992071814 hasConceptScore W1992071814C185544564 @default.
- W1992071814 hasConceptScore W1992071814C185592680 @default.
- W1992071814 hasConceptScore W1992071814C2776382133 @default.
- W1992071814 hasConceptScore W1992071814C42296456 @default.
- W1992071814 hasConceptScore W1992071814C544153396 @default.
- W1992071814 hasConceptScore W1992071814C66887884 @default.
- W1992071814 hasConceptScore W1992071814C75473681 @default.
- W1992071814 hasIssue "0" @default.
- W1992071814 hasLocation W19920718141 @default.
- W1992071814 hasOpenAccess W1992071814 @default.
- W1992071814 hasPrimaryLocation W19920718141 @default.
- W1992071814 hasRelatedWork W104224454 @default.
- W1992071814 hasRelatedWork W1977741966 @default.
- W1992071814 hasRelatedWork W1989779906 @default.
- W1992071814 hasRelatedWork W2016972415 @default.
- W1992071814 hasRelatedWork W2042193334 @default.
- W1992071814 hasRelatedWork W2070552562 @default.
- W1992071814 hasRelatedWork W2532465105 @default.
- W1992071814 hasRelatedWork W3169298362 @default.
- W1992071814 hasRelatedWork W3214185074 @default.
- W1992071814 hasRelatedWork W4223613871 @default.
- W1992071814 hasVolume "0" @default.
- W1992071814 isParatext "false" @default.
- W1992071814 isRetracted "false" @default.
- W1992071814 magId "1992071814" @default.
- W1992071814 workType "article" @default.