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- W1992085229 abstract "Organylthioenynes have became useful synthons recently, due their possible applications on the synthesis of enediynes and thiophenes. Recently the preparation of (Z)-thiobutenynes through hydrothiolation of 1,3-diacetylenes using NaBH4 and C4H9SSC4H9 to generate nucleophilic sulfur species such as BuS- and PhS- was reported by us. This systematic study allowed us to understand the limitations and potential of this methodology in the preparation of (Z)-thiobutenynes. However, (Z)- thiobutenyne 2, was obtained in low yield (40%) using this methodology." @default.
- W1992085229 created "2016-06-24" @default.
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- W1992085229 date "2013-09-01" @default.
- W1992085229 modified "2023-10-01" @default.
- W1992085229 title "Synthesis of (Z)-thiobutenynes using NaOH or TBAOH as activator: a comparative study" @default.
- W1992085229 doi "https://doi.org/10.5151/chempro-14bmos-r0382-1" @default.
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