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• W1992092254 abstract "The blue shift of the benzenoid-to-quinoid exciton transition (BQET) in thin films of the emeraldine base (EB) of polyaniline (PANI) observed earlier has been studied in more detail in order to explain its origin. It was found that the shift is partly reversible upon annealing of the films or their exposure to solvent vapors. Infra-red (IR) absorption spectra of the films did not reveal features attributable to the pernigraniline base (PB) of polyaniline. It has been proposed that direct interaction of planar benzenoid and quinoid chromophore groups rather than oxidation of the polymer chains is responsible for the blue-shifted exciton transition in thin polyaniline films." @default.
• W1992092254 created "2016-06-24" @default.
• W1992092254 creator A5031916182 @default.
• W1992092254 date "2001-12-01" @default.
• W1992092254 modified "2023-09-27" @default.
• W1992092254 title "Origin of the exciton transition shift in thin films of polyaniline" @default.
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• W1992092254 doi "https://doi.org/10.1016/s0379-6779(01)00475-1" @default.
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