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• W1992123075 abstract "By using 2-mercapto-5-n-propylpyrimidine (MPP) as capping ligands, copper nanoclusters with different core sizes were prepared using a chemical reduction method. The as-prepared copper nanoclusters were loaded onto a glassy carbon electrode and their size effect on the electrocatalytic activity towards the oxygen reduction reaction (ORR) was investigated with electrochemical techniques in alkaline electrolyte. Cyclic voltammetric (CV) studies showed that the onset potential of ORR on smaller copper nanoclusters is more positive than that on larger copper nanoclusters. Compared to the larger clusters, higher current density of ORR was obtained using the smaller copper nanoclusters. These CV results indicate that the smaller Cu nanoclusters exhibit higher catalytic performance for ORR. In rotating-disk voltammetric studies, ORR on the synthesized MPP monolayer-protected copper nanoclusters is mainly dominated by a two-electron transfer pathway to produce H2O2." @default.
• W1992123075 created "2016-06-24" @default.
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• W1992123075 date "2013-03-01" @default.
• W1992123075 modified "2023-09-23" @default.
• W1992123075 title "Size-dependent catalytic activity of copper nanoclusters for oxygen electroreduction in alkaline solution" @default.
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• W1992123075 doi "https://doi.org/10.1080/19475411.2012.670140" @default.
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