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- W1992124310 abstract "A new chiral S,N-heterobidentate thiourea−oxazoline ligand was synthesized and isolated as two atropoisomers (4a, 4b). The ligands were employed in Pd-catalyzed enantioselective bis(alkoxycarbonylation)s of terminal olefins under mild conditions, giving high yields and modest ee values, demonstrating the potential of such ligands for use in Pd-catalyzed carbonylative reactions. Molecular structures of 4a and of the PdCl2 complexes of 4a and 4b have been determined by single-crystal X-ray diffraction. In both complexes, the ligands exhibit a bidentate S,N bonding mode." @default.
- W1992124310 created "2016-06-24" @default.
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- W1992124310 date "2007-08-11" @default.
- W1992124310 modified "2023-10-11" @default.
- W1992124310 title "Synthesis of Thiourea−Oxazolines, a New Class of Chiral S,N-Heterobidentate Ligands: Application in Pd-Catalyzed Asymmetric Bis(methoxycarbonylation) of Terminal Olefins" @default.
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- W1992124310 doi "https://doi.org/10.1021/om700311x" @default.
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