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• W1992133092 endingPage "13200" @default.
• W1992133092 startingPage "13193" @default.
• W1992133092 abstract "We propose an extended jellium model which includes the most important features of the noble metals. The density of states is modeled by the superposition of a d band and an s-like conduction band. The redistribution of some of the d electrons into the conduction band as an effect of the s-d hybridization is taken into account, and the conduction band includes 1.5 electrons per atom. We show that the occupation number ${Z}_{d}$ of the d band is mainly determined by the ratio ${W}_{d}$/(${ensuremath{varepsilon}}_{F}$-${ensuremath{varepsilon}}_{d}$), where ${W}_{d}$, ${ensuremath{varepsilon}}_{d}$, and ${ensuremath{varepsilon}}_{F}$ are, respectively, the width and the center of the d band and the energy of the Fermi level. The shift of the d-band center between the bulk metal and the surface plane is related to the narrowing of the d band of the surface plane, and we deduce an estimate of the d-band contribution to the work function. In the present model the position of the Fermi level and of the d-band center are reproduced, and the result for the work function of Cu and Ag is satisfactory." @default.
• W1992133092 created "2016-06-24" @default.
• W1992133092 creator A5004814392 @default.
• W1992133092 creator A5034173614 @default.
• W1992133092 date "1989-06-15" @default.
• W1992133092 modified "2023-09-25" @default.
• W1992133092 title "Calculation of the electronic work function of Cu and Ag from an extended jellium model" @default.
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• W1992133092 doi "https://doi.org/10.1103/physrevb.39.13193" @default.
• W1992133092 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/9948218" @default.
• W1992133092 hasPublicationYear "1989" @default.
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