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• W1992133620 abstract "The first tris(pyrrolyl)phosphine-substituted alkyne−dicobaltcarbonyl complexes have been prepared by reaction of the corresponding dicobalthexacarbonyl complexes with tris(pyrrolyl)phosphine, and their solid-state structures have been studied by X-ray diffraction. In accordance with the strong π-acceptor character of the tris(pyrrolyl)phosphine ligand, these complexes present a Pauson−Khand reactivity very similar to that of the parent, unsubstituted ones. On the other hand, the cobalt-stabilized propargyl cations derived from tris(pyrrolyl)phosphine-substituted (2-propynol)dicobaltcarbonyl complexes undergo an unprecedented intramolecular Nicholas reaction in which one of the pyrrole rings acts as an internal nucleophile, and that gives rise to a new structural type of chelated alkyne−dicobaltcarbonyl complexes." @default.
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• W1992133620 date "2000-04-06" @default.
• W1992133620 modified "2023-10-03" @default.
• W1992133620 title "Tris(pyrrolyl)phosphine-Substituted Acetylene−Dicobaltcarbonyl Complexes: Syntheses, Structural Characterization, and Reactivity Studies" @default.
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• W1992133620 doi "https://doi.org/10.1021/om990914y" @default.
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