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Matches in SemOpenAlex for { <https://semopenalex.org/work/W1992138840> ?p ?o ?g. }

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• W1992138840 abstract "Long-range electron transfer is usually treated by coupling donor and acceptor states perturbatively to high-energy intermediate states (superexchange). This needs modification when intermediate-state energies approach the initial—final state crossing. We present a formalism for three-level systems with strong electronic—vibrational coupling in the three states and covering all intermediate-state energies. The “normal” superexchange form is recovered at high energies. Finite resonance appear as the intermediate state traverses the initial—final state crossing. Still lower energies cause intermediate-state population but the process differs from sequential electron transfer due to intermediate-state vibrational nonequilibrium and electronic coupling to both donor and acceptor." @default.
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• W1992138840 date "1991-07-01" @default.
• W1992138840 modified "2023-10-10" @default.
• W1992138840 title "Resonance effects in three-centre long-range electron transfer" @default.
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• W1992138840 doi "https://doi.org/10.1016/0009-2614(91)80107-9" @default.
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