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- W1992196573 abstract "Hydrogen environment-assisted cracking (HEAC) of Monel K-500 is quantified using slow-rising stress intensity loading with electrical potential monitoring of small crack propagation and elastoplastic J-integral analysis. For this loading, with concurrent crack tip plastic strain and H accumulation, aged Monel K-500 is susceptible to intergranular HEAC in NaCl solution when cathodically polarized at −800 mVSCE (E A, vs saturated calomel) and lower. Intergranular cracking is eliminated by reduced cathodic polarization more positive than −750 mVSCE. Crack tip diffusible H concentration rises, from near 0 wppm at E A of −765 mVSCE, with increasing cathodic polarization. This behavior is quantified by thermal desorption spectroscopy and barnacle cell measurements of hydrogen solubility vs overpotential for planar electrodes, plus measured-local crevice potential, and pH scaled to the crack tip. Using crack tip H concentration, excellent agreement is demonstrated between measurements and decohesion-based model predictions of the E A dependencies of threshold stress intensity and Stage II growth rate. A critical level of cathodic polarization must be exceeded for HEAC to occur in aged Monel K-500. The damaging-cathodic potential regime likely shifts more negative for quasi-static loading or increasing metallurgical resistance to HEAC." @default.
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- W1992196573 date "2014-05-17" @default.
- W1992196573 modified "2023-10-02" @default.
- W1992196573 title "Measurement and Modeling of Hydrogen Environment-Assisted Cracking in Monel K-500" @default.
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