Matches in SemOpenAlex for { <https://semopenalex.org/work/W1992203313> ?p ?o ?g. }
Showing items 1 to 84 of
84
with 100 items per page.
- W1992203313 endingPage "1405" @default.
- W1992203313 startingPage "1400" @default.
- W1992203313 abstract "The crystal structure of [(C5H4BMe2)2Fe]-4,4′-bipyridine [2 · bipy]n has been determined by the method of simulated annealing from high resolution X-ray powder diffraction at room temperature. The compound is of interest, because it proves that highly ordered organometallic macromolecules can be formed in the solid state via the self-assembly of N–B-donor-acceptor bonds. [2 · bipy]n crystallizes in the triclinic space group, P 1, Z = 2, with unit cell parameters of a = 8.3366(2) Å, b = 11.4378(3) Å, c = 12.6740(5) Å, α = 112.065(2)°, β = 108.979(1)°, γ = 90.551(2)°, and V = 1047.06(6) Å3. For the structure solution of [2 · bipy]n 11 degrees of freedom (3 translational, 3 orientational, 5 torsion angles) were determined within several hours, demonstrating that the crystal packing and the molecular conformation of medium sized (< 50 non-hydrogen atoms) coordination compounds can nowadays be solved routinely from high resolution powder diffraction data. Die Kristallstruktur des Polymers [(C5H4BMe2)2Fe]-4,4′-Bipyridin mittels hochaufgelöster Röntgenpulverbeugung Die Kristallstruktur von [(C5H4BMe2)2Fe]-4,4′-bipyridine [2 · bipy]n wurde mittels der Methode des Simulated Annealing aus hochauflösenden Röntgenbeugungsaufnahmen an Pulvern bei Raumtemperatur gelöst. Die Verbindung ist von Interesse, da sie beweist, daß sich hoch geordnete metallorganische Makromoleküle über N–B-Donor-Akzeptor Bindungen im Festkörper bilden können. [2 · bipy]n kristallisiert in der triklinen Raumgruppe P 1 (Z = 2) mit Gitterparametern von a = 8.3366(2) Å, b = 11.4378(3) Å, c = 12.6740(5) Å, α = 112.065(2)°, β = 108.979(1)°, γ = 90.551(2)° und V = 1047.06(6) Å3. Bei der Kristallstrukturbestimmung von [2 · bipy]n wurden 11 Freiheitsgrade (3 der Translation, 3 der Rotation und 5 Torsionswinkel) innerhalb einiger Stunden bestimmt, womit gezeigt werden kann, daß Kristallpackung und Molekülkonformation mittelgroßer Koordinationsverbindungen (< 50 NichtWasserstoff Atome) heutzutage routinemäßig aus hochauflösenden Pulverbeugungsdaten gelöst werden können." @default.
- W1992203313 created "2016-06-24" @default.
- W1992203313 creator A5024851520 @default.
- W1992203313 creator A5062267065 @default.
- W1992203313 creator A5070746137 @default.
- W1992203313 creator A5076753690 @default.
- W1992203313 creator A5088627937 @default.
- W1992203313 date "2000-06-01" @default.
- W1992203313 modified "2023-09-27" @default.
- W1992203313 title "Crystal Structure of the [(C5H4BMe2)2Fe]-4,4′-bipyridine Polymer from High Resolution X-Ray Powder Diffraction" @default.
- W1992203313 cites W1521042556 @default.
- W1992203313 cites W1672911329 @default.
- W1992203313 cites W2171776966 @default.
- W1992203313 cites W2914275007 @default.
- W1992203313 doi "https://doi.org/10.1002/(sici)1521-3749(200006)626:6<1400::aid-zaac1400>3.0.co;2-8" @default.
- W1992203313 hasPublicationYear "2000" @default.
- W1992203313 type Work @default.
- W1992203313 sameAs 1992203313 @default.
- W1992203313 citedByCount "42" @default.
- W1992203313 countsByYear W19922033132012 @default.
- W1992203313 countsByYear W19922033132013 @default.
- W1992203313 countsByYear W19922033132014 @default.
- W1992203313 countsByYear W19922033132020 @default.
- W1992203313 countsByYear W19922033132022 @default.
- W1992203313 countsByYear W19922033132023 @default.
- W1992203313 crossrefType "journal-article" @default.
- W1992203313 hasAuthorship W1992203313A5024851520 @default.
- W1992203313 hasAuthorship W1992203313A5062267065 @default.
- W1992203313 hasAuthorship W1992203313A5070746137 @default.
- W1992203313 hasAuthorship W1992203313A5076753690 @default.
- W1992203313 hasAuthorship W1992203313A5088627937 @default.
- W1992203313 hasConcept C112887158 @default.
- W1992203313 hasConcept C115624301 @default.
- W1992203313 hasConcept C120665830 @default.
- W1992203313 hasConcept C121332964 @default.
- W1992203313 hasConcept C178790620 @default.
- W1992203313 hasConcept C185039092 @default.
- W1992203313 hasConcept C185592680 @default.
- W1992203313 hasConcept C192562407 @default.
- W1992203313 hasConcept C207114421 @default.
- W1992203313 hasConcept C2779336533 @default.
- W1992203313 hasConcept C2781002295 @default.
- W1992203313 hasConcept C32909587 @default.
- W1992203313 hasConcept C42228675 @default.
- W1992203313 hasConcept C50515024 @default.
- W1992203313 hasConcept C73922627 @default.
- W1992203313 hasConcept C8010536 @default.
- W1992203313 hasConceptScore W1992203313C112887158 @default.
- W1992203313 hasConceptScore W1992203313C115624301 @default.
- W1992203313 hasConceptScore W1992203313C120665830 @default.
- W1992203313 hasConceptScore W1992203313C121332964 @default.
- W1992203313 hasConceptScore W1992203313C178790620 @default.
- W1992203313 hasConceptScore W1992203313C185039092 @default.
- W1992203313 hasConceptScore W1992203313C185592680 @default.
- W1992203313 hasConceptScore W1992203313C192562407 @default.
- W1992203313 hasConceptScore W1992203313C207114421 @default.
- W1992203313 hasConceptScore W1992203313C2779336533 @default.
- W1992203313 hasConceptScore W1992203313C2781002295 @default.
- W1992203313 hasConceptScore W1992203313C32909587 @default.
- W1992203313 hasConceptScore W1992203313C42228675 @default.
- W1992203313 hasConceptScore W1992203313C50515024 @default.
- W1992203313 hasConceptScore W1992203313C73922627 @default.
- W1992203313 hasConceptScore W1992203313C8010536 @default.
- W1992203313 hasIssue "6" @default.
- W1992203313 hasLocation W19922033131 @default.
- W1992203313 hasOpenAccess W1992203313 @default.
- W1992203313 hasPrimaryLocation W19922033131 @default.
- W1992203313 hasRelatedWork W1977900997 @default.
- W1992203313 hasRelatedWork W2004470015 @default.
- W1992203313 hasRelatedWork W2045568882 @default.
- W1992203313 hasRelatedWork W2049473277 @default.
- W1992203313 hasRelatedWork W2091660553 @default.
- W1992203313 hasRelatedWork W2121789822 @default.
- W1992203313 hasRelatedWork W2371540792 @default.
- W1992203313 hasRelatedWork W2904148684 @default.
- W1992203313 hasRelatedWork W2942835415 @default.
- W1992203313 hasRelatedWork W3011641519 @default.
- W1992203313 hasVolume "626" @default.
- W1992203313 isParatext "false" @default.
- W1992203313 isRetracted "false" @default.
- W1992203313 magId "1992203313" @default.
- W1992203313 workType "article" @default.