Matches in SemOpenAlex for { <https://semopenalex.org/work/W1992212676> ?p ?o ?g. }
Showing items 1 to 90 of
90
with 100 items per page.
- W1992212676 endingPage "12048" @default.
- W1992212676 startingPage "12044" @default.
- W1992212676 abstract "The influence of the host lattice on the chemical bonding nature of guest iodine species in high-Tc superconducting I−Bi2Sr1.5-xLaxCa1.5Cu2Oy nanohybrids has been examined by performing combinative X-ray photoelectron spectroscopic (XPS) and X-ray absorption spectroscopic (XAS) analyses. The iodine species were found to possess two kinds of oxidation states, negatively charged iodine (Iδ-) and highly oxidized heptavalent iodine (I+VII). The concentration of heptavalent iodine species is significantly increased by replacing Sr+II ions with La+III ions, indicating that excess oxygen in the host lattice oxidizes the intercalated iodine into heptavalent iodine species. From mass spectroscopic analysis for disintercalated species, it is certain that the heptavalent iodine exists as a periodate IO4- cluster in easily removable sites such as the edge or surface of crystallite. The I LI-edge XAS analyses reveal that even in heavily La-substituted compounds the content of the negatively charged iodide species is still greater than that of the periodate species. The degree of charge transfer between host and guest is also found to depend on La content, which makes it possible to explain the Tc behavior of iodine intercalates with respect to La substitution. The present study provides an intriguing example for the possible control of the bonding nature of guest species through a modification of the composition of the host lattice." @default.
- W1992212676 created "2016-06-24" @default.
- W1992212676 creator A5002221770 @default.
- W1992212676 creator A5011102304 @default.
- W1992212676 creator A5065443386 @default.
- W1992212676 date "2004-07-08" @default.
- W1992212676 modified "2023-10-16" @default.
- W1992212676 title "Influence of Host Lattice on the Chemical Bonding Nature of Guest Species in High-<i>T</i><sub>c</sub> Superconducting I−Bi<sub>2</sub>Sr<sub>1.5-</sub><i><sub>x</sub></i>La<i><sub>x</sub></i>Ca<sub>1.5</sub>Cu<sub>2</sub>O<i><sub>y</sub></i> Nanohybrids" @default.
- W1992212676 cites W1529423760 @default.
- W1992212676 cites W1609458457 @default.
- W1992212676 cites W1990143116 @default.
- W1992212676 cites W1991750923 @default.
- W1992212676 cites W2010760760 @default.
- W1992212676 cites W2013310924 @default.
- W1992212676 cites W2016472625 @default.
- W1992212676 cites W2025532275 @default.
- W1992212676 cites W2028552873 @default.
- W1992212676 cites W2031969833 @default.
- W1992212676 cites W2033937964 @default.
- W1992212676 cites W2037900194 @default.
- W1992212676 cites W2044101840 @default.
- W1992212676 cites W2046098102 @default.
- W1992212676 cites W2053523944 @default.
- W1992212676 cites W2054289882 @default.
- W1992212676 cites W2065139483 @default.
- W1992212676 cites W2073616789 @default.
- W1992212676 cites W2093316804 @default.
- W1992212676 cites W2167590372 @default.
- W1992212676 cites W2255068721 @default.
- W1992212676 cites W2471593725 @default.
- W1992212676 cites W2950250812 @default.
- W1992212676 cites W2952301106 @default.
- W1992212676 doi "https://doi.org/10.1021/jp047908m" @default.
- W1992212676 hasPublicationYear "2004" @default.
- W1992212676 type Work @default.
- W1992212676 sameAs 1992212676 @default.
- W1992212676 citedByCount "2" @default.
- W1992212676 crossrefType "journal-article" @default.
- W1992212676 hasAuthorship W1992212676A5002221770 @default.
- W1992212676 hasAuthorship W1992212676A5011102304 @default.
- W1992212676 hasAuthorship W1992212676A5065443386 @default.
- W1992212676 hasConcept C119824511 @default.
- W1992212676 hasConcept C121332964 @default.
- W1992212676 hasConcept C145148216 @default.
- W1992212676 hasConcept C175708663 @default.
- W1992212676 hasConcept C178790620 @default.
- W1992212676 hasConcept C179104552 @default.
- W1992212676 hasConcept C185592680 @default.
- W1992212676 hasConcept C2776789926 @default.
- W1992212676 hasConcept C2778870691 @default.
- W1992212676 hasConcept C46141821 @default.
- W1992212676 hasConcept C539932907 @default.
- W1992212676 hasConcept C62284982 @default.
- W1992212676 hasConcept C62520636 @default.
- W1992212676 hasConcept C8010536 @default.
- W1992212676 hasConceptScore W1992212676C119824511 @default.
- W1992212676 hasConceptScore W1992212676C121332964 @default.
- W1992212676 hasConceptScore W1992212676C145148216 @default.
- W1992212676 hasConceptScore W1992212676C175708663 @default.
- W1992212676 hasConceptScore W1992212676C178790620 @default.
- W1992212676 hasConceptScore W1992212676C179104552 @default.
- W1992212676 hasConceptScore W1992212676C185592680 @default.
- W1992212676 hasConceptScore W1992212676C2776789926 @default.
- W1992212676 hasConceptScore W1992212676C2778870691 @default.
- W1992212676 hasConceptScore W1992212676C46141821 @default.
- W1992212676 hasConceptScore W1992212676C539932907 @default.
- W1992212676 hasConceptScore W1992212676C62284982 @default.
- W1992212676 hasConceptScore W1992212676C62520636 @default.
- W1992212676 hasConceptScore W1992212676C8010536 @default.
- W1992212676 hasIssue "32" @default.
- W1992212676 hasLocation W19922126761 @default.
- W1992212676 hasOpenAccess W1992212676 @default.
- W1992212676 hasPrimaryLocation W19922126761 @default.
- W1992212676 hasRelatedWork W1988957513 @default.
- W1992212676 hasRelatedWork W2024763689 @default.
- W1992212676 hasRelatedWork W2035934612 @default.
- W1992212676 hasRelatedWork W2043692508 @default.
- W1992212676 hasRelatedWork W2071130978 @default.
- W1992212676 hasRelatedWork W2088018059 @default.
- W1992212676 hasRelatedWork W2129071178 @default.
- W1992212676 hasRelatedWork W2332518268 @default.
- W1992212676 hasRelatedWork W2953126590 @default.
- W1992212676 hasRelatedWork W4220868419 @default.
- W1992212676 hasVolume "108" @default.
- W1992212676 isParatext "false" @default.
- W1992212676 isRetracted "false" @default.
- W1992212676 magId "1992212676" @default.
- W1992212676 workType "article" @default.