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• W1992244932 abstract "The electrochemical behaviour of Ni(II) on the mercury electrode in the presence of dimethylglyoxime was investigated in weakly alkaline media by different techniques. The occurrence of the voltammetric peak could be ascribed to the reduction of nickel from its adsorbed state as the bis(dimethylglyoximato)nickel(II) complex. The position of the peak is pH dependent and the peak height is proportional to the surface concentration of Ni(DMG)2. Adsorption equilibria could be expressed at low coverages by simple Langmuir type isotherms. The kinetic parameters for the totally irreversible charge transfer process suggest that the rate determining step is the transfer of the second electron to the absorbed intermediate." @default.
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• W1992244932 date "1986-12-01" @default.
• W1992244932 modified "2023-09-25" @default.
• W1992244932 title "Electrochemical reduction of Ni(II) on the hanging mercury drop electrode in the presence of dimethylglyoxime" @default.
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• W1992244932 doi "https://doi.org/10.1016/0022-0728(86)80094-8" @default.
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