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- W1992245835 abstract "Bis(dimethylglyoxime)copper(II), CuII(DMGH)2, is readily oxidized to the corresponding copper(III) complex. Cyclic voltammetry exhibited quasi-reversible one-electron transfer with peak-to-peak separation of ≈ 80 mV. The E1/2 value varied linearly with −log[H+] with a slope of −59 mV, showing the involvement of one proton in the electrode reaction. The kinetics of the oxidation of CuII(DMGH)2 by CuIII(H−2DGEN)+ (DGEN = diglycylethylenediamine) showed a first-order dependence on both the reductant and the oxidant. The second-order rate constant, k2, varies with [H+] according to: k2=k′2+k3/[H+]. The mechanism of electron transfer is discussed in terms of inner- and outer-sphere mechanisms." @default.
- W1992245835 created "2016-06-24" @default.
- W1992245835 creator A5065838919 @default.
- W1992245835 date "1989-01-01" @default.
- W1992245835 modified "2023-09-26" @default.
- W1992245835 title "Electron transfer between bis(dimethylglyoxime)copper(II) and diglycylethylenediamine copper(III). Stabilization of copper(III) by a dioxime ligand" @default.
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- W1992245835 doi "https://doi.org/10.1016/s0277-5387(89)80003-8" @default.
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