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- W1992304465 abstract "The reaction between vanadium(III) and hydrogen peroxide in aqueous acidic solutions was investigated. The rate law shows first-order dependences on both vanadium(III) and hydrogen peroxide concentrations, with a rate constant, defined in terms of -d[H(2)O(2)]/dt, of 2.06 +/- 0.03 L mol(-)(1) s(-)(1) at 25 degrees C; the rate is independent of hydrogen ion concentration. The varying reaction stoichiometry, the appreciable evolution of dioxygen, the oxidation of 2-PrOH to acetone, and the inhibition of acetone formation by the hydroxyl radical scavengers, dimethyl sulfoxide and sodium benzoate, point to a Fenton mechanism as the predominant pathway in the reaction. Methyltrioxorhenium(VII) does not appear to catalyze this reaction. A second-order rate constant for the oxidation of V(3+) by OV(O(2))(+) was determined to be 11.3 +/- 0.3 L mol(-)(1) s(-)(1) at 25 degrees C. An overall reaction scheme consisting of over 20 reactions, in agreement with the experimental results and literature reports, was established by kinetic simulation studies." @default.
- W1992304465 created "2016-06-24" @default.
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- W1992304465 date "2005-06-28" @default.
- W1992304465 modified "2023-10-13" @default.
- W1992304465 title "Oxidation of Vanadium(III) by Hydrogen Peroxide and the Oxomonoperoxo Vanadium(V) Ion in Acidic Aqueous Solutions: A Kinetics and Simulation Study" @default.
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- W1992304465 doi "https://doi.org/10.1021/ic050502j" @default.
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