Matches in SemOpenAlex for { <https://semopenalex.org/work/W1992317495> ?p ?o ?g. }
Showing items 1 to 86 of
86
with 100 items per page.
- W1992317495 abstract "The rate of replacement of nickel by copper ions from NN'-ethylenebis(salicylideneiminato)nickel(II) has been found to depend on the copper salt used in the reaction, the rate decreasing in the order Cu(ClO4)2 > CuCl2 > Cu(CH3C00)2 in 2-methoxyethanol at 70�. The position of equilibrium also varies with the salt used, the percentage exchange decreasing Cu(ClO4)2 > Cu(CH3OO)2 > CuCl2. The rate data are explained by assuming a bimolecular reaction step involving copper ions reacting with a partly dissociated nickel complex. The positions of equilibrium are related to the competition for copper and nickel ions by anions in solution as well as the quadridentate ligand. The rate of reaction is also dependent on the solvent used, increasing with increase in dielectric constant. This is taken as evidence that a preliminary dissociation of at least one nickel-ligand bond is of importance in the overall exchange process." @default.
- W1992317495 created "2016-06-24" @default.
- W1992317495 creator A5031013132 @default.
- W1992317495 creator A5014936929 @default.
- W1992317495 date "1963-01-01" @default.
- W1992317495 modified "2023-09-24" @default.
- W1992317495 title "The Exchange of Metal Ions with Quadridentate Complexes. I. The Effects of Metal Salts and Solvents" @default.
- W1992317495 doi "https://doi.org/10.1071/ch9630779" @default.
- W1992317495 hasPublicationYear "1963" @default.
- W1992317495 type Work @default.
- W1992317495 sameAs 1992317495 @default.
- W1992317495 citedByCount "3" @default.
- W1992317495 crossrefType "journal-article" @default.
- W1992317495 hasAuthorship W1992317495A5014936929 @default.
- W1992317495 hasAuthorship W1992317495A5031013132 @default.
- W1992317495 hasConcept C102931765 @default.
- W1992317495 hasConcept C116569031 @default.
- W1992317495 hasConcept C121332964 @default.
- W1992317495 hasConcept C145148216 @default.
- W1992317495 hasConcept C147789679 @default.
- W1992317495 hasConcept C148898269 @default.
- W1992317495 hasConcept C161790260 @default.
- W1992317495 hasConcept C170493617 @default.
- W1992317495 hasConcept C175113610 @default.
- W1992317495 hasConcept C178790620 @default.
- W1992317495 hasConcept C179104552 @default.
- W1992317495 hasConcept C185592680 @default.
- W1992317495 hasConcept C199164860 @default.
- W1992317495 hasConcept C2776371256 @default.
- W1992317495 hasConcept C2780471494 @default.
- W1992317495 hasConcept C504270822 @default.
- W1992317495 hasConcept C544153396 @default.
- W1992317495 hasConcept C544778455 @default.
- W1992317495 hasConcept C55493867 @default.
- W1992317495 hasConcept C62520636 @default.
- W1992317495 hasConcept C65024703 @default.
- W1992317495 hasConcept C93391505 @default.
- W1992317495 hasConceptScore W1992317495C102931765 @default.
- W1992317495 hasConceptScore W1992317495C116569031 @default.
- W1992317495 hasConceptScore W1992317495C121332964 @default.
- W1992317495 hasConceptScore W1992317495C145148216 @default.
- W1992317495 hasConceptScore W1992317495C147789679 @default.
- W1992317495 hasConceptScore W1992317495C148898269 @default.
- W1992317495 hasConceptScore W1992317495C161790260 @default.
- W1992317495 hasConceptScore W1992317495C170493617 @default.
- W1992317495 hasConceptScore W1992317495C175113610 @default.
- W1992317495 hasConceptScore W1992317495C178790620 @default.
- W1992317495 hasConceptScore W1992317495C179104552 @default.
- W1992317495 hasConceptScore W1992317495C185592680 @default.
- W1992317495 hasConceptScore W1992317495C199164860 @default.
- W1992317495 hasConceptScore W1992317495C2776371256 @default.
- W1992317495 hasConceptScore W1992317495C2780471494 @default.
- W1992317495 hasConceptScore W1992317495C504270822 @default.
- W1992317495 hasConceptScore W1992317495C544153396 @default.
- W1992317495 hasConceptScore W1992317495C544778455 @default.
- W1992317495 hasConceptScore W1992317495C55493867 @default.
- W1992317495 hasConceptScore W1992317495C62520636 @default.
- W1992317495 hasConceptScore W1992317495C65024703 @default.
- W1992317495 hasConceptScore W1992317495C93391505 @default.
- W1992317495 hasLocation W19923174951 @default.
- W1992317495 hasOpenAccess W1992317495 @default.
- W1992317495 hasPrimaryLocation W19923174951 @default.
- W1992317495 hasRelatedWork W1490259359 @default.
- W1992317495 hasRelatedWork W1524126500 @default.
- W1992317495 hasRelatedWork W1974902111 @default.
- W1992317495 hasRelatedWork W1976126540 @default.
- W1992317495 hasRelatedWork W1981207805 @default.
- W1992317495 hasRelatedWork W1985165768 @default.
- W1992317495 hasRelatedWork W1993097019 @default.
- W1992317495 hasRelatedWork W1996830019 @default.
- W1992317495 hasRelatedWork W2025668849 @default.
- W1992317495 hasRelatedWork W2054510227 @default.
- W1992317495 hasRelatedWork W2054876515 @default.
- W1992317495 hasRelatedWork W214477670 @default.
- W1992317495 hasRelatedWork W2460745753 @default.
- W1992317495 hasRelatedWork W2531375724 @default.
- W1992317495 hasRelatedWork W2894842818 @default.
- W1992317495 hasRelatedWork W2945538658 @default.
- W1992317495 hasRelatedWork W2952296355 @default.
- W1992317495 hasRelatedWork W2956130721 @default.
- W1992317495 hasRelatedWork W52839823 @default.
- W1992317495 hasRelatedWork W857120073 @default.
- W1992317495 isParatext "false" @default.
- W1992317495 isRetracted "false" @default.
- W1992317495 magId "1992317495" @default.
- W1992317495 workType "article" @default.