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- W1992321447 abstract "Abstract Compartmentalization and nitroxide partitioning in NMP in dispersed systems have been investigated by modeling and simulations. Compartmentalization comprises the segregation effect on termination and the confined space effect on deactivation. Under certain conditions, it is possible to obtain an improvement in both control and livingness. The particle size threshold for compartmentalization, decreases with any system change that leads to a decrease in the number of propagating radicals and/or nitroxides per particle, and vice versa. There is direct competition between the confined space effect on deactivation and nitroxide exit–the more water‐soluble the nitroxide, the weaker the confined space effect. Nitroxide partitioning leads to an increase in polymerization rate and loss in control/livingness. magnified image" @default.
- W1992321447 created "2016-06-24" @default.
- W1992321447 creator A5017973525 @default.
- W1992321447 date "2010-02-01" @default.
- W1992321447 modified "2023-10-17" @default.
- W1992321447 title "Nitroxide‐Mediated Radical Polymerization in Dispersed Systems: Compartmentalization and Nitroxide Partitioning" @default.
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- W1992321447 doi "https://doi.org/10.1002/mats.200900051" @default.
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